화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.17, No.3, 521-526, May, 2011
Preparation of ultrastrength nanopapers using cellulose nanofibrils
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Cellulose nanofibrils were manufactured from cellulose powder (45 μm particle size) using a high pressure homogenizer with various pass numbers. In the present study, the cellulose nanofibrils were used to prepare nanopapers of extremely high tensile performance. Chemical modifications with the increased pass number through the homogenizer provided the dramatically increased tensile modulus and strength of the nanopapers. The high tensile properties are related to the increased surface area, improved crystallinity, hydrogen bonding sites by the homogenization, 3-dimension network structure between the cellulose nanofibrils, and improved stress distribution during the tensile test.
  1. Fengel D, Wegner G, Wood . Chemistry, Ultrastructure Reactions, Walter de Gruyter, Berlin, New York (1989)
  2. Klemm D, Schumann D, Kramer F, Hebler N, Hornung M, Schmauder HP, Marsch S, Adv. Polym. Sci., 205, 49 (2006)
  3. Eichhorn SJ, Dufresne A, Aranguren M, Marcovich NE, Capadona JR, Rowan SJ, Weder C, Thielemans W, Roman M, Renneckar S, Gindl W, Veigel S, Keckes J, Yano H, Abe K, Nogi M, Nakagaito AN, Mangalam A, Simonsen J, Benight AS, Bismarck A, Berglund LA, Peijs T, J. Mater. Sci., 45(1), 1 (2010)
  4. Zimmerman T, Po¨ hler E, Schwaller P, Adv. Eng. Mater., 12, 1156 (2005)
  5. Lee SY, Chun SJ, Kang IA, Park JY, J. Ind. Eng. Chem., 15(1), 50 (2009)
  6. Henriksson M, Berglund LA, Isaksson P, Lindstrom T, Nishino T, Biomacromolecules, 9(6), 1579 (2008)
  7. Nakagaito AN, Yano H, Appl. Phys. A., 78, 547 (2004)
  8. Taniguchi T, Okamura K, Polym. Int., 47, 291 (1998)
  9. Abe K, Iwamoto S, Yano H, Biomacromolecules, 8(10), 3276 (2007)
  10. Saito T, Nishiyama Y, Putaux JL, Vignon M, Isogai A, Biomacromolecules, 7(6), 1687 (2006)
  11. Ichazo MN, Alberno A, Gonzalez J, Perera R, Canal MV, Compos. Struct., 54, 207 (2001)
  12. Lee SY, Chun SJ, Doh GH, Kang IA, Paik KH, J. Compos. Mater., 43, 1639 (2009)
  13. Stepanova GA, Pakshver AB, Kaller AL, Ponomareva MA, Polyakova GV, Goikhman AS, Fibre Chem., 13, 405 (1982)
  14. Belgacem MN, Gandini A, Compos. Interfaces, 12(1-2), 41 (2005)
  15. Goncalves G, Marques PAAP, Trindade T, Pascoal C, Gandini A, J. Colloid Interface Sci., 324(1-2), 42 (2008)
  16. Henriksson M, Berglund LA, Isaksson P, Lindstrom T, Nishino T, Biomacromolecules, 9(6), 1579 (2008)
  17. Grobe A, in: Branrup J, Immergut EH (Eds.), 3rd ed., Polymer Handbook, Wiley Publisher, New York (1989)
  18. Rong MZ, Zhang MQ, Liu Y, Yang GC, Zeng HM, Compos. Sci. Technol., 61, 1437 (2001)