화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.19, No.9, 951-964, September, 2011
DOI10.1007/s13233-011-0907-8  Export Citation
Multi Functionalization of Polypropylene with Controlled Degradation and Its Structure Characterization
Shuangshuang Wang, Na Wang, Li Meng, Jiruo Zhao†, and Ying Feng
  • Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-Plastics, Qingdao University of Science & Technology, Qingdao, 266042, People’s Republic of China
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The multi functionalization of isotactic polypropylenes (iPP) with glycidyl methacrylate (GMA) was carried out by in situ chlorinating graft copolymerization (ISCGC), in which chlorine (Cl2) is used as a radical initiator as well as a radical scavenger. The molecular weight measurement indicates that functionalized iPP with controlled degradation could be obtained because the unstable radicals that induce iPP degradation could be terminated quickly by chlorine. Owing to the unique allyl-containing structure of GMA, multi functionalized iPP could be synthesized under the effect of chlorine, which contained both epoxy groups and C=C double bonds as well as trace amount of chlorine atoms in the functionalized polymer structure. The structure of both the functionalization polymer and homopolymer formed in this system were analyzed by FTIR and 1H NMR. The mechanism of grafting reaction, iPP chain degradation, and GMA homopolymer formation scheme in ISCGC were proposed. The thermal properties of the functionalized polymer are also discussed.
Keywords:polypropylene (PP);functionalization of polymers;graft copolymers;glycidyl methacrylate;structure.
  1. Saxena S, Ray AR, Gupta B, J. Appl. Polym. Sci., 116(5), 2884 (2010)
  2. Dong ZX, Liu ZM, Han BX, He J, Jiang T, Yang GY, J. Mater. Chem., 12, 3565 (2002)
  3. Shi D, Chen HB, Li RKY, J. Mater. Sci., 42(22), 9495 (2007)
  4. Pan B, Viswanathan K, Hoyle CE, Moore RB, J. Polym. Sci. A: Polym. Chem., 42(8), 1953 (2004)
  5. Zhu YT, An LJ, Jiang W, Macromolecules, 36(10), 3714 (2003)
  6. Zhang RH, Zhu YT, Zhang JG, Jiang W, Yin JH, J. Polym. Sci. A: Polym. Chem., 43(22), 5529 (2005)
  7. Abacha N, Fellahi S, Polym. Int., 54, 909 (2005)
  8. Liu T, Hu GH, Tong GS, Zhao L, Cao GP, Yuan WK, Ind. Eng. Chem. Res., 44(12), 4292 (2005)
  9. Galia A, De Gregorio R, Spadaro G, Scialdone O, Filardo G, Macromolecules, 37(12), 4580 (2004)
  10. Parent JS, Sengupta SS, Macromolecules, 38(13), 5538 (2005)
  11. Wang J, Wang DF, Du W, Zou EG, Dong Q, J. Appl. Polym. Sci., 113(3), 1803 (2009)
  12. Burton EL, Woodhead M, Coates P, Gough T, J. Appl. Polym. Sci., 117(5), 2707 (2010)
  13. Verenich S, Paul S, Pourdeyhimi B, J. Appl. Polym. Sci., 108(5), 2983 (2008)
  14. Sun YJ, Hu GH, Lambla M, J. Appl. Polym. Sci., 57, 1043 (1994)
  15. Huang H, Liu NC, J. Appl. Polym. Sci., 67(12), 1957 (1998)
  16. Cartier H, Hu GH, J. Polym. Sci. A: Polym. Chem., 36(7), 1053 (1998)
  17. Xie XM, Chen NH, Guo BH, Li S, Polym. Int., 49, 1677 (2000)
  18. Cartier H, Hu GH, J. Mater. Sci., 35(8), 1985 (2000)
  19. Paul S, Verenich S, Pourdeyhimi B, Polym. Int., 57, 975 (2008)
  20. Ao YH, Tang K, Xu N, Yang HD, Zhang HX, Polym. Bull., 59(2), 279 (2007)
  21. Wei Q, Chionna D, Galoppini E, Pracella M, Macromol. Chem. Phys., 204, 1123 (2003)
  22. Pracella M, Chionna D, Macromol. Symp., 218, 173 (2004)
  23. Pietrasanta Y, Robin JJ, Torres N, Boutevin B, Macromol. Chem. Phys., 200, 142 (1999)
  24. Zhang LY, Fan GQ, Guo CY, Dong JY, Hu YL, Huang MB, Polym. Int., 55, 675 (2006)
  25. Wang ZM, Hong H, Chung TC, Macromolecules, 38(22), 8966 (2005)
  26. Lu B, Chung TC, Macromolecules, 32(8), 2525 (1999)
  27. Coiai S, Passaglia E, Aglietto M, Ciardelli F, Macromolecules, 37(22), 8414 (2004)
  28. Bae C, Hartwig JF, Harris NKB, Long RO, Anderson KS, Hillmyer MA, J. Am. Chem. Soc., 127(2), 767 (2005)
  29. Zhu LC, Tang GB, Shi Q, Cai CL, Yin JH, J. Polym. Sci. B: Polym. Phys., 44(1), 134 (2006)
  30. Zhao JR, Li JY, Feng Y, Yin JH, Polym. Adv. Technol., 18, 822 (2007)
  31. Zhang L, Sun YY, Ma YQ, Zhao JR, Feng Y, Yin JH, Polym. Bull., 63(3), 341 (2009)
  32. Brandrup J, Immergut EH, in Polymer Handbook, 4th ed., Wiley, New York, 1999, p VII 10.
  33. Rzaev ZMO, Yilmazbayhan A, Alper E, Adv. Polym. Sci., 26, 41 (2007)
  34. De Roover B, Sclavons M, Carlier V, Devaux J, Legras R, Momtaz A, J. Polym. Sci. A: Polym. Chem., 33(5), 829 (1995)
  35. De Roover B, Devaux J, Legras R, J. Polym. Sci. A: Polym. Chem., 34(7), 1195 (1996)
  36. Bettini SHP, Agnelli JAM, J. Appl. Polym. Sci., 74(2), 247 (1999)
  37. Bettini SHP, Agnelli JAM, J. Appl. Polym. Sci., 85(13), 2706 (2002)
  38. Canamero PF, de la Fuente JL, Madruga EL, Fernandez-Garclia M, Macromol. Chem. Phys., 205, 2221 (2004)
  39. Pretsch E, Buhlmann P, Affolter C, in Structure Determination of Organic Compounds Tables of Spectral Data, 3rd ed., Springer-Verlag publishers, Heidelberg, 2000, p 11.
  40. Xiao HW, Yu FY, Yu Y, Huang SQ, J. Appl. Polym. Sci., 104(4), 2515 (2007)
  41. De La Fuente JL, Canamero PF, Fernandez-Garcia M, J. Polym. Sci. A: Polym. Chem., 44(6), 1807 (2006)