Inorganic Chemistry, Vol.35, No.25, 7440-7442, 1996
Rb-2(Ga-4(HPO4)(PO4)(4))Center-Dot-0.5H(2)O - A New Gallium Phosphate-Containing 4-Coordinated, 5-Coordinated, and 6-Coordinated Gallium Atoms
The synthesis and structure of a new gallium phosphate is described; the framework structure consists of four-, five-, and six-coordinated Ga atoms linked by phosphate groups to form eight-membered rings that house the rubidium cations and water molecules, and which are connected to give rise to infinite channels with eight-membered windows along [100].
Keywords:OCTAHEDRAL-TETRAHEDRAL FRAMEWORK;X-RAY CHARACTERIZATION;CRYSTAL-STRUCTURE;MICROPOROUS GALLOPHOSPHATE;ETHYLENEDIAMINE;ISOPROPYLAMINE