Effect of Palladium Ion on Facilitated Olefin Transport through Silver-Polymer Complex Membranes

Hye Hun Park; Jongok Won; Sung Gyu Pyo; Hansoo Park

Macromolecular Research, Vol.19, No.10, 1077-1081, October, 2011

DOI10.1007/s13233-011-1001-y Export Citation

Effect of Palladium Ion on Facilitated Olefin Transport through Silver-Polymer Complex Membranes

Hye Hun Park, Jongok Won¹, Sung Gyu Pyo², and Hansoo Park^{2, †}

Korea Institute of Science and Technology, Seoul, 136-791, Korea
¹Department of Applied Chemistry, Sejong University, Seoul, 143-747, Korea
²School of Integrative Engineering, Chung-Ang University, Seoul, 156-756, Korea

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This study examined the effect of palladium (Pd) ions on the performance and stability of silver-polymer complex membranes composed of AgBF4 and poly(N-vinyl pyrrolidone) (PVP) for the separation of propylene/propane mixtures. The separation performances including the selectivity of propylene/propane and mixed gas permeance through the PVP/AgBF4 membrane decreased continuously due mainly to the reduction of silver ions to silver nano-particles. On the other hand, upon the addition of Pd ions, enhanced membrane stability along with the higher separation performance was achieved. This demonstrates that Pd ions play a role in preventing the reduction of silver ions and participating directly in the facilitated propylene transport. UV analysis of the membranes shows that the rate of silver nano-particle formation was retarded significantly by the addition of Pd salts.

Keywords:palladium;silver;polymer;membrane;facilitated transport.

[References]

Eldridge RB, Ind. Eng. Chem. Res., 32, 2208 (1993)
Ho WS, Dalrymple DC, J. Membr. Sci., 91(1-2), 13 (1994)
Beverwijk CDM, Kerk GVD, Leusink AJ, Noltes JG, Organomet. Chem. Rev. A, 5, 215 (1970)
Bai S, Sridhar S, Khan AA, J. Membr. Sci., 147(1), 131 (1998)
Yamaguchi T, Kurita H, Nakao S, J. Phys. Chem. B, 103(11), 1831 (1999)
Yang JS, Hsiue GH, J. Membr. Sci., 138(2), 203 (1998)
Choi S, Kim JH, Kang YS, Macromolecules, 34(26), 9087 (2001)
Hong SU, Jin JH, Won J, Kang YS, Adv. Mater., 12(13), 968 (2000)
Jin JH, Hong SU, Won J, Kang YS, Macromolecules, 33(13), 4932 (2000)
Kim CK, Kim CK, Lee BS, Won J, Kim HS, Kang YS, J. Phys. Chem. A, 105(39), 9024 (2001)
Kim JH, Min BR, Kim CK, Won J, Kang YS, Macromolecules, 34(17), 6052 (2001)
Kim JH, Min BR, Kim CK, Won J, Kang YS, Macromolecules, 35(13), 5250 (2002)
Kim JH, Min BR, Kim CK, Won J, Kang YS, J. Phys. Chem. B, 106(10), 2786 (2002)
Kim JH, Min BR, Won J, Kang YS, Chem. Eur. J., 8, 650 (2002)
Pinnau I, Toy LG, Casillas C, U. S. Patent, 5,670,051 (1997).
Jose B, Ryu JH, Kim YJ, Kim H, Kang YS, Lee SD, Kim HS, Chem. Mater., 14, 2134 (2002)
Jose B, Ryu JH, Lee BG, Lee H, Kang YS, Kim HS, Chem. Commun., 2046 (2001)
Huang HH, Ni XP, Loy GL, Chew CH, Tan KL, Loh FC, Deng JF, Xu GQ, Langmuir, 12(4), 909 (1996)
Silvert PY, HerreraUrbina R, Duvauchelle N, Vijayakrishnan V, Elhsissen KT, J. Mater. Chem., 6, 573 (1996)
Zhang ZT, Zhao B, Hu LM, J. Solid State Chem., 121, 105 (1996)
Kim HS, Ryu JH, Jose B, Lee BG, Ahn BS, Kang YS, Langmuir, 17(19), 5817 (2001)
Pastoriza-Santos I, Liz-Marzan LM, Langmuir, 15(4), 948 (1999)
Bard AJ, Faulkener LR, Electrochemical Methods: Fundamentals and Applications, Wiley & Sons, New York, 1980.
Zhao MQ, Crooks RM, Chem. Mater., 11, 3379 (1999)
Bradley JS, The Chemistry of Transition Metal Colloids, Wiley-VCH Verlag GmbH, Weinheim, 2007.
Davis SC, Klabunde KJ, Chem. Rev., 82, 153 (1982)
Gates BC, Guczi L, Knozinger H, Studies in Surface Science and Catalysis, Elsevier, Amsterdam, 1986, Vol. 29.

[Referenced By]

[1] Eldridge RB, Ind. Eng. Chem. Res., 32, 2208 (1993)

[2] Ho WS, Dalrymple DC, J. Membr. Sci., 91(1-2), 13 (1994)

[3] Beverwijk CDM, Kerk GVD, Leusink AJ, Noltes JG, Organomet. Chem. Rev. A, 5, 215 (1970)

[4] Bai S, Sridhar S, Khan AA, J. Membr. Sci., 147(1), 131 (1998)

[5] Yamaguchi T, Kurita H, Nakao S, J. Phys. Chem. B, 103(11), 1831 (1999)

[6] Yang JS, Hsiue GH, J. Membr. Sci., 138(2), 203 (1998)

[7] Choi S, Kim JH, Kang YS, Macromolecules, 34(26), 9087 (2001)

[8] Hong SU, Jin JH, Won J, Kang YS, Adv. Mater., 12(13), 968 (2000)

[9] Jin JH, Hong SU, Won J, Kang YS, Macromolecules, 33(13), 4932 (2000)

[10] Kim CK, Kim CK, Lee BS, Won J, Kim HS, Kang YS, J. Phys. Chem. A, 105(39), 9024 (2001)

[11] Kim JH, Min BR, Kim CK, Won J, Kang YS, Macromolecules, 34(17), 6052 (2001)

[12] Kim JH, Min BR, Kim CK, Won J, Kang YS, Macromolecules, 35(13), 5250 (2002)

[13] Kim JH, Min BR, Kim CK, Won J, Kang YS, J. Phys. Chem. B, 106(10), 2786 (2002)

[14] Kim JH, Min BR, Won J, Kang YS, Chem. Eur. J., 8, 650 (2002)

[15] Pinnau I, Toy LG, Casillas C, U. S. Patent, 5,670,051 (1997).

[16] Jose B, Ryu JH, Kim YJ, Kim H, Kang YS, Lee SD, Kim HS, Chem. Mater., 14, 2134 (2002)

[17] Jose B, Ryu JH, Lee BG, Lee H, Kang YS, Kim HS, Chem. Commun., 2046 (2001)

[18] Huang HH, Ni XP, Loy GL, Chew CH, Tan KL, Loh FC, Deng JF, Xu GQ, Langmuir, 12(4), 909 (1996)

[19] Silvert PY, HerreraUrbina R, Duvauchelle N, Vijayakrishnan V, Elhsissen KT, J. Mater. Chem., 6, 573 (1996)

[20] Zhang ZT, Zhao B, Hu LM, J. Solid State Chem., 121, 105 (1996)

[21] Kim HS, Ryu JH, Jose B, Lee BG, Ahn BS, Kang YS, Langmuir, 17(19), 5817 (2001)

[22] Pastoriza-Santos I, Liz-Marzan LM, Langmuir, 15(4), 948 (1999)

[23] Bard AJ, Faulkener LR, Electrochemical Methods: Fundamentals and Applications, Wiley & Sons, New York, 1980.

[24] Zhao MQ, Crooks RM, Chem. Mater., 11, 3379 (1999)

[25] Bradley JS, The Chemistry of Transition Metal Colloids, Wiley-VCH Verlag GmbH, Weinheim, 2007.

[26] Davis SC, Klabunde KJ, Chem. Rev., 82, 153 (1982)

[27] Gates BC, Guczi L, Knozinger H, Studies in Surface Science and Catalysis, Elsevier, Amsterdam, 1986, Vol. 29.