Inorganic Chemistry, Vol.37, No.5, 1105-1111, 1998
Synthesis and characterization of unsymmetrical (cis-(phosphino-arsino)ethene)tetracarbonylmolybdenum complexes : Hydroarsination reactions of (H3CC CPPh2)Mo(CO)(5) and [H2C=C=CH(DBP)]Mo(CO)(5) and hydrophosphination reactions of (Ph2AsCH2C CH)Mo(CO)(5)
The base-catalyzed hydroarsination reactions of (H3CC=CPPh2)Mo(CO)(5) and [H2C=C=CH(DBP)]Mo(CO)(5) (DBP=dibenzophosphole) give several different products as a function of reaction conditions. These products have been characterized by elemental analyses, physical properties, H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy, and, in two cases, X-ray crystallography.
Keywords:CATALYSIS