Inorganic Chemistry, Vol.37, No.7, 1651-1654, 1998
Silver(I) assisted metal exchange reaction. A generalized synthesis of tris-chelated copper(II) complexes of neutral N,N-donors
A novel and direct synthetic route for the syntheses of hexacoordinated cupric complexes involving bidentate N,N-donor ligands has been elaborated. This synthetic strategy has been successfully applied for the preparation of mixed-ligand tris(chelates).pathways and that reaction from the lowest lying LF triplet level occurs with a greatly reduced photoefficiency. W(CO)(4)(en) h nu-->CH3CN W(CO)(3)(en)(CH3CN) + CO