A two-dimensional network constructed via hydrogen-bonded cross-linkages of molybdenum oxide chains

Zapf PJ; LaDuca RL; Rarig RS; Johnson KM; Zubieta J

Inorganic Chemistry, Vol.37, No.13, 3411-3414, 1998

Zapf PJ, LaDuca RL, Rarig RS, Johnson KM, Zubieta J

The hydrothermal reaction of MoO3 and 4,4'-bipyridylamine yields [Mo4O13(Hbpa)(2)], a two-dimensional material constructed from molybdenum oxide chains linked through hydrogen bonding of the protonated pendant arms of the Hbpa(+) ligand.

Keywords:HYDROTHERMAL SYNTHESIS;CRYSTAL-STRUCTURE;SOLIDS;4;4'-BIPYRIDINE;FRAMEWORK;POLYMERS;CHANNELS;CATIONS;LIGANDS;COMPLEX