Fabrication and application of silicalite-1 and TS-1 hollow fibers with polyethylene imine (PEI) fibers as substrates

Zhongliang Sun; Yongming Zhang; Xiangyun Deng; Jianbao Li; Chunrong Xiong

Journal of Industrial and Engineering Chemistry, Vol.18, No.1, 92-97, January, 2012

DOI10.1016/j.jiec.2011.11.083 Export Citation

Fabrication and application of silicalite-1 and TS-1 hollow fibers with polyethylene imine (PEI) fibers as substrates

Zhongliang Sun^{1, 2}, Yongming Zhang¹, Xiangyun Deng¹, Jianbao Li¹, and Chunrong Xiong^{1, †}

¹Key Laboratory of Ministry of Education for Application Technology of Chemical Materials in Hainan Superior Resources, Hainan University, Haikou 570228, PR China
²School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China

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Silicalite-1 and titanium containing silicalite-1 (TS-1) hollow fibers were fabricated with polyethylene imine (PEI) fibers as substrates. The acid treated PEI fibers were positively charged and can be effectively coated with silicalite-1 or TS-1 nanocrystals from their colloidal solution. The adsorbed silicalite-1 or TS-1 nanocrystals grew up and became more compact upon two days of vapor phase Ostwald ripening in autoclave. Silicalite-1 and TS-1 hollow fibers were obtained after calcination at 400 ℃ in air. The shell thickness of the hollow fibers is ~ 1 mm. Hydroxylation of phenol with H2O2 was investigated over TS-1 based catalysts in order to compare influences of nanocrystals composed macrostructure and Al2O3 binder on the catalytic activities.

Keywords:Hollow fibers;Polyethylene imine (PEI) fibers;Silicalite-1;TS-1

[References]

Schmidt I, Madsen C, Jacobsen CJH, Inorg. Chem., 39(11), 2279 (2000)
Yu T, Wang X, Li H, Petro. Sci. Technol., 25, 1125 (2007)
Xiong C, Kim MJ, Balkus KJ, Small., 2, 52 (2006)
Okada K, Kuboyama K, Takei T, Kameshima Y, Yasumori A, Yoshimura M, Micropor. Mesopor. Mater., 37, 99 (2000)
Nijhuis TA, Beers AEW, Vergunst T, Hoek I, Kapteijn F, Moulijn JA, Catal. Rev.-Sci. Eng., 43(4), 345 (2001)
Williams JL, Catal. Today, 69(1-4), 3 (2001)
Jasra RV, Choudary NV, Bhat SGT, Sep. Sci. Technol., 26, 885 (1991)
Ozcan A, Kalipcilar H, Ind. Eng. Chem. Res., 45(14), 4977 (2006)
Valtchev V, Schoeman BJ, Hedlund J, Mintova S, J. Sterte, Zeolites., 17, 408 (1996)
Wang YJ, Tang Y, Wang XD, Yang WL, Gao Z, Chem. Lett., 29(11), 1344 (2000)
Song W, Kanthasamy R, Grassian VH, Larsen SC, Chem. Commun., 1920 (2004)
Xiong C, Coutinho D, Balkus KJ, Micropor. Mesopor. Mater., 86, 14 (2005)
Dong A, Wang Y, Wang D, Yang W, Zhang Y, Ren N, Gao Z, Tang Y, Micropor.Mesopor. Mater., 64, 69 (2003)
Kanthasamy R, Barquist K, Larsen SC, Micropor. Mesopor. Mater., 113, 554 (2008)
Shin YJ, Kim SH, Yang DH, Kwon H, Shin JS, J. Ind. Eng. Chem., 16(3), 380 (2010)
Esposito A, Taramasso M, Neri C, Buonomo F, UK Pat. 2 116 974 (1985)
Thangaraj A, Kumar R, Ratnasamy P, Appl. Catal., L-1. (1990)
Tatsumi T, Nakamura M, Negishi S, Tominaga HJ, Chem. Commun., 476 (1990)
Huybrechts DRC, Bruycker De L, Jacobs PA, Nature., 345, 240 (1990)
Wan YSS, Gavriilidis A, Yeung KL, Trans. IchemE., 81, 753 (2003)
Roffia P, Padovan M, Moretti E, De Alberti G, EP 208 311 (1987)
Reddy JS, Jacobs PA, Catal. Lett., 37(3-4), 213 (1996)
Tonti S, Roffia P, Cesana A, Mantegazza MA, Padovan M, EP 0 314 147 (1988)
Reddy JS, Jacobs PA, J. Chem. Soc. Perkin Trans., I22, 2665 (1993)
Thangaraj A, Kumar R, Mirajkar SP, Ratnasamy P, J. Catal., 130, 1 (1991)
Kraushaar B, Vanhooff JHC, Catal. Lett., 1, 81 (1988)
Wilkenhoner U, Langhendries G, van Laar F, Baron GV, Gammon DW, Jacobs PA, van Steen E, J. Catal., 203(1), 201 (2001)
Tuel A, Moussa-Khouzami S, Ben Taarit Y, Naccache C, J. Mol. Catal., 68, 45 (1991)
Tanarungsun G, Kiatkittipong W, Praserthdam P, Yamada H, Tagawa T, Assabumrungrat S, J. Ind. Eng. Chem., 14(5), 596 (2008)

[Referenced By]

[1] Schmidt I, Madsen C, Jacobsen CJH, Inorg. Chem., 39(11), 2279 (2000)

[2] Yu T, Wang X, Li H, Petro. Sci. Technol., 25, 1125 (2007)

[3] Xiong C, Kim MJ, Balkus KJ, Small., 2, 52 (2006)

[4] Okada K, Kuboyama K, Takei T, Kameshima Y, Yasumori A, Yoshimura M, Micropor. Mesopor. Mater., 37, 99 (2000)

[5] Nijhuis TA, Beers AEW, Vergunst T, Hoek I, Kapteijn F, Moulijn JA, Catal. Rev.-Sci. Eng., 43(4), 345 (2001)

[6] Williams JL, Catal. Today, 69(1-4), 3 (2001)

[7] Jasra RV, Choudary NV, Bhat SGT, Sep. Sci. Technol., 26, 885 (1991)

[8] Ozcan A, Kalipcilar H, Ind. Eng. Chem. Res., 45(14), 4977 (2006)

[9] Valtchev V, Schoeman BJ, Hedlund J, Mintova S, J. Sterte, Zeolites., 17, 408 (1996)

[10] Wang YJ, Tang Y, Wang XD, Yang WL, Gao Z, Chem. Lett., 29(11), 1344 (2000)

[11] Song W, Kanthasamy R, Grassian VH, Larsen SC, Chem. Commun., 1920 (2004)

[12] Xiong C, Coutinho D, Balkus KJ, Micropor. Mesopor. Mater., 86, 14 (2005)

[13] Dong A, Wang Y, Wang D, Yang W, Zhang Y, Ren N, Gao Z, Tang Y, Micropor.Mesopor. Mater., 64, 69 (2003)

[14] Kanthasamy R, Barquist K, Larsen SC, Micropor. Mesopor. Mater., 113, 554 (2008)

[15] Shin YJ, Kim SH, Yang DH, Kwon H, Shin JS, J. Ind. Eng. Chem., 16(3), 380 (2010)

[16] Esposito A, Taramasso M, Neri C, Buonomo F, UK Pat. 2 116 974 (1985)

[17] Thangaraj A, Kumar R, Ratnasamy P, Appl. Catal., L-1. (1990)

[18] Tatsumi T, Nakamura M, Negishi S, Tominaga HJ, Chem. Commun., 476 (1990)

[19] Huybrechts DRC, Bruycker De L, Jacobs PA, Nature., 345, 240 (1990)

[20] Wan YSS, Gavriilidis A, Yeung KL, Trans. IchemE., 81, 753 (2003)

[21] Roffia P, Padovan M, Moretti E, De Alberti G, EP 208 311 (1987)

[22] Reddy JS, Jacobs PA, Catal. Lett., 37(3-4), 213 (1996)

[23] Tonti S, Roffia P, Cesana A, Mantegazza MA, Padovan M, EP 0 314 147 (1988)

[24] Reddy JS, Jacobs PA, J. Chem. Soc. Perkin Trans., I22, 2665 (1993)

[25] Thangaraj A, Kumar R, Mirajkar SP, Ratnasamy P, J. Catal., 130, 1 (1991)

[26] Kraushaar B, Vanhooff JHC, Catal. Lett., 1, 81 (1988)

[27] Wilkenhoner U, Langhendries G, van Laar F, Baron GV, Gammon DW, Jacobs PA, van Steen E, J. Catal., 203(1), 201 (2001)

[28] Tuel A, Moussa-Khouzami S, Ben Taarit Y, Naccache C, J. Mol. Catal., 68, 45 (1991)

[29] Tanarungsun G, Kiatkittipong W, Praserthdam P, Yamada H, Tagawa T, Assabumrungrat S, J. Ind. Eng. Chem., 14(5), 596 (2008)