화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.18, No.1, 152-159, January, 2012
DOI10.1016/j.jiec.2011.11.008  Export Citation
LSER modeling of extraction of succinic acid by tridodecylamine dissolved in 2-octanone and 1-octanol
Ismail Inci, Y. Selim Asc†, and Hasan Uslu1
  • Engineering Faculty, Chemical Engineering Department, Istanbul University, 34320, Istanbul, Turkey
  • 1Engineering & Architecture Faculty, Chemical Engineering Department, Beykent University, Ayazaga koyu, Istanbul, Turkey
E-mail:
Reactive extraction can be used for the recovery of carboxylic acids from fermentation broth. Through the formation of complex with extractants at the two-phase interface, the carboxylic acids are partitioned into organic solvents. But, the recovery of carboxylic acids is interrupted by the conditions of fermentation broth. In this work, kinetic studies for the extraction of succinic acid from aqueous solution with tridodecylamine diluted in 2-octanone and 1-octanol have been carried out. Equilibrium and kinetic studies for the extraction of succinic acid from aqueous solution with tridodecylamine diluted in two functional groups (alcohol and ketone) such as 2-octanone and 1-octanol are reported. All measurements have been carried out at 298.15 K. The results of the liquid.liquid equilibrium measurements have been correlated by a linear solvation energy relationship . LSER model which takes into account physical interactions.
Keywords:Succinic acid;LSER;Tridodecylamine;2-Octanon;1-Octanol
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