Based on the enthalpy-porosity technique, a model of thermal conduction accompanied with solidification and melting processes is developed and numerically analyzed to investigate the thermal response of the brick wall filled with phase change materials (PCM). The thermal response, which is represented by indoor wall surface temperature response, of brick wall filled with PCM is evaluated and compared with that of solid brick wall. The effects of PCM filling and its filling amount on thermal response of brick wall are investigated and discussed. It is indicated that, compared to the common solid brick wall, the thermal storage of brick wall filled with PCM is elevated by the alternate process of melting and solidification under fluctuating outdoor temperatures. The use of PCM in the brick walls is beneficial for the thermal insulation, temperature hysteresis and thermal comfort for occupancy. In addition, with the increasing filling amount of PCM, the fluctuation of indoor wall surface temperature is significantly smoothed. Correspondingly, the hysteresis in response to the outdoor temperature fluctuation is enhanced. Moreover, the present model is verified by experimental data available in the literature. (C) 2011 Elsevier B.V. All rights reserved.