KOH 활성화처리된 메조기공 탄소를 이용한 실내 포름알데히드 제거

유미진; 박성훈; 전종기; 박영권; Mi Jin Yu; Sung Hoon Park; Jong-Ki Jeon; Young-Kwon Park

Applied Chemistry for Engineering, Vol.23, No.1, 42-46, February, 2012

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KOH 활성화처리된 메조기공 탄소를 이용한 실내 포름알데히드 제거

Removal of Indoor Formaldehyde Using Mesoporous Carbon Activated with KOH

유미진, 박성훈 ¹, 전종기 ², 박영권 ^†

서울시립대학교 환경공학부
¹순천대학교 환경공학과
²공주대학교 화학공학부

Mi Jin Yu, Sung Hoon Park¹, Jong-Ki Jeon², and Young-Kwon Park^†

School of Environmental Engineering, University of Seoul, Seoul 130-743, Korea
¹Department of Environmental Engineering, Sunchon National University, Suncheon 540-742, Korea
²Department of Chemical Engineering, Kongju National University, Cheonan 331-717, Korea

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초록

본 연구에서는 메조기공 탄소(CMK-3)를 KOH로 활성화 하여 실내공기 오염물질인 포름알데히드 흡착에 사용하였다. 활성화는 KOH 처리한 CMK-3를 700 ℃의 반응기에서 질소분위기로 수행하였다. 활성화된 시료의 특성은 BET, XRD, XPS, FT.IR을 통해 분석하였다. 포름알데히드의 흡착능은 활성화에 의해 향상되었으며, 이는 활성화에 의해 메조기공탄소의 산소작용기와 질소 작용기의 생성에 기인하는 것으로 판단된다.

In this study, a mesoporous carbon (CMK-3) activated using KOH was applied to the adsorption of formaldehyde, a representative indoor air pollutant. Activation process was carried out by putting KOH.treated CMK.3 in a reactor maintained at 700 °C in N2 atmosphere. The activated sample was characterized using BET, XRD, XPS and FT.IR analysis. The formaldehyde adsorption performance of the mesoporous carbon was improved, which is attributed to the formation of oxygen and nitrogen functional groups on the mesoporous carbon surface by the activation process.

Keywords:formaldehyde;CMK-3;KOH;adsorption

[References]

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Shin SK, Kang JH, Song JH, J. Korean Soc. Environ.Eng., 32, 963 (2010)
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Kang M, Kim D, Yi SH, Han JU, Yie JE, Kim JM, Catal. Today., 93, 695 (2004)
Ryoo R, Joo SH, Jun S, J. Phys. Chem. B, 103(37), 7743 (1999)
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Kang M, Yi SH, Lee HI, Yie JE, Kim JM, Chem.Commun., 1944 (2002)
Fuertes AB, Nevskaia DM, Micropor. Mesopor. Mater., 62, 177 (2003)
Ryoo R, Jun S, J. Korean Ind. Eng. Chem., 12(1), 1 (2001)
An HB, Yu MJ, Kim JM, Jin M, Jeon JK, Park SH, Kim SS, Park YK, Nanoscale Res. Lett., 7, 7 (2012)
Yim JH, Kim DI, Bae JA, Park YK, Park JH, Jeon JK, Park SH, Song J, Kim SS, J. Nanosci. Nanotechnol., 11, 1714 (2011)
Lee JY, Park SH, Jeon JK, Yoo KS, Kim SS, Park YK, Korean J. Chem. Eng., 28, 1556 (2001)
Darmstadt H, Roy C, Kaliaguine S, Choi SJ, Ryoo R, Carbon., 40, 2673 (2002)
Xia YD, Mokaya R, Adv. Mater., 16(17), 1553 (2004)
Kilic M, Keskin ME, Mazlum S, Mazlum N, Int. J. Miner.Process., 87, 1 (2008)
Shafeeyan MS, Daud WMAW, Houshmand A, Shamiri A, J. Anal. Appl. Pyrolysis., 89, 143 (2010)

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[1] Kim DI, Park JH, Kim SD, Lee JY, Yim JH, Jeon JK, Park SH, Park YK, J. Ind. Eng. Chem., 17(1), 1 (2011)

[2] Kim SS, Kang DH, Choi DH, Yeo MS, Kim KW, Building Environ., 43, 320 (2008)

[3] Shin SK, Kang JH, Song JH, J. Korean Soc. Environ.Eng., 32, 963 (2010)

[4] Lim JK, Lee SW, Kam SK, Lee DW, Lee MG, J. Environ. Sci., 14, 61 (2005)

[5] Lee H, Kim J, Han C, Song HK, Na BK, HWAHAK KONGHAK, 37(1), 120 (1999)

[6] Kang M, Kim D, Yi SH, Han JU, Yie JE, Kim JM, Catal. Today., 93, 695 (2004)

[7] Ryoo R, Joo SH, Jun S, J. Phys. Chem. B, 103(37), 7743 (1999)

[8] Jun S, Joo SH, Ryoo R, Kruk M, Jaroniec M, Liu Z, Ohsuna T, Terasaki O, J. Am. Chem. Soc., 122(43), 10712 (2000)

[9] Kang M, Yi SH, Lee HI, Yie JE, Kim JM, Chem.Commun., 1944 (2002)

[10] Fuertes AB, Nevskaia DM, Micropor. Mesopor. Mater., 62, 177 (2003)

[11] Ryoo R, Jun S, J. Korean Ind. Eng. Chem., 12(1), 1 (2001)

[12] An HB, Yu MJ, Kim JM, Jin M, Jeon JK, Park SH, Kim SS, Park YK, Nanoscale Res. Lett., 7, 7 (2012)

[13] Yim JH, Kim DI, Bae JA, Park YK, Park JH, Jeon JK, Park SH, Song J, Kim SS, J. Nanosci. Nanotechnol., 11, 1714 (2011)

[14] Lee JY, Park SH, Jeon JK, Yoo KS, Kim SS, Park YK, Korean J. Chem. Eng., 28, 1556 (2001)

[15] Darmstadt H, Roy C, Kaliaguine S, Choi SJ, Ryoo R, Carbon., 40, 2673 (2002)

[16] Xia YD, Mokaya R, Adv. Mater., 16(17), 1553 (2004)

[17] Kilic M, Keskin ME, Mazlum S, Mazlum N, Int. J. Miner.Process., 87, 1 (2008)

[18] Shafeeyan MS, Daud WMAW, Houshmand A, Shamiri A, J. Anal. Appl. Pyrolysis., 89, 143 (2010)