ABS-Polyethylene 혼합물의 저온 열분해 특성평가

최홍준; 정상문; 이봉희; Hong-Jun Choi; Sang Mun Jeong; Bong-Hee Lee

Korean Chemical Engineering Research, Vol.50, No.2, 223-228, April, 2012

Export Citation

ABS-Polyethylene 혼합물의 저온 열분해 특성평가

Liquefaction Characteristics of ABS-polyethylene Mixture by a Low-Temperature Pyrolysis

최홍준, 정상문, 이봉희 ^†

충북대학교 화학공학과, 361-763 충북 청주시 흥덕구 성봉로 410

Hong-Jun Choi, Sang Mun Jeong, and Bong-Hee Lee^†

Department of Chemical Engineering, Chungbuk National University, 410 Sungbong-ro, Heungduk-gu, Cheongju-si, Chungbuk 361-763, Korea

E-mail:

초록

ABS와 폴리에틸렌(Polyethylene, PE) 및 ABS-PE 혼합물의 저온열분해를 회분식 반응기를 이용하여 상압 및 450 ℃에서 실행하였다. 열분해 시간은 20~80분까지 하였고 열분해로 생성된 성분은 지식경제부에서 고시한 증류성상온도에 따라 가스, 가솔린, 등유, 경유, 중유로 분류하였다. ABS와 PE의 혼합 폐플라스틱의 열분해 전환율은 PE의 함량이 증가할수록 증가하는 것으로 나타났다. 열분해생성물의 수율은 PE의 함량이 높을수록 중유 > 가스 > 가솔린 > 경유 >등유 순으로 회수되었다.

The low-temperature pyrolysis of ABS, polyethylene (PE) and an ABS-polyethylene (ABS-PE) mixture was conducted in a batch reactor at 450 ℃. The conversion and the product yield were measured as a function of the reaction time with a variation of the mixture composition. The oil products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of the Ministry of Knowledge Economy. The pyrolysis conversion increases with an increase in the content of PE. The yield of the pyrolytic products was ranked as heavy oil>gas>gasoline>gas oil>kerosene as the content of PE in the mixture increases.

Keywords:ABS;Polyethylene;Pyrolysis;Yield;Liquefaction

[References]

Lee KH, Nam KY, Clean Technol., 15(3), 186 (2009)
Ryu DS, Kweon SS, Lee HS, Lee CK, J. Ksee., 23(2), 207 (2001)
Lee BH, Yu HJ, Kim DS, Polym.(Korea), 29(1), 64 (2005)
Choi HJ, Jeong SM, Lee BH, Korean Chem. Eng. Res., 49(4), 417 (2011)
Eng FP, Ishida H, J. Appl.Polym. Sci., 32(5), 5021 (1986)
Oh SC, Ryu JH, Kwak H, Bae SY, Lee KH, J. Korean Ind. Eng. Chem., 19(2), 191 (2008)
Sugimura Y, Tsuge S, Macromolecules., 12(3), 512 (1979)
Scott, DS, Czernik SR, Piskorz J, Radlein AG, Energ. Fuel., 4(4), 407 (1990)
Encinar JM, Gonzalez JF, Fuel Process. Technol., 89(7), 678 (2008)
Brebu M, Bhaskar T, Murai K, Muto A, Sakata Y, Uddin MA, Fuel., 83(14), 2021 (2004)
McNeill IC, Thermal Degradation, Pergamon Press, Oxford, 55 (1989)
Williams PT, Williams EA, J. Anal. Appl. Pyrolysis., 51, 107 (1999)
Bhaskar T, Murai K, Matsui T, Brebu MA, Uddin MA, Muto A, Sakata Y, Murata K, J. Anal. Appl. Pyrolysis., 70, 369 (2003)

[Related Articles]

[1] Lee KH, Nam KY, Clean Technol., 15(3), 186 (2009)

[2] Ryu DS, Kweon SS, Lee HS, Lee CK, J. Ksee., 23(2), 207 (2001)

[3] Lee BH, Yu HJ, Kim DS, Polym.(Korea), 29(1), 64 (2005)

[4] Choi HJ, Jeong SM, Lee BH, Korean Chem. Eng. Res., 49(4), 417 (2011)

[5] Eng FP, Ishida H, J. Appl.Polym. Sci., 32(5), 5021 (1986)

[6] Oh SC, Ryu JH, Kwak H, Bae SY, Lee KH, J. Korean Ind. Eng. Chem., 19(2), 191 (2008)

[7] Sugimura Y, Tsuge S, Macromolecules., 12(3), 512 (1979)

[8] Scott, DS, Czernik SR, Piskorz J, Radlein AG, Energ. Fuel., 4(4), 407 (1990)

[9] Encinar JM, Gonzalez JF, Fuel Process. Technol., 89(7), 678 (2008)

[10] Brebu M, Bhaskar T, Murai K, Muto A, Sakata Y, Uddin MA, Fuel., 83(14), 2021 (2004)

[11] McNeill IC, Thermal Degradation, Pergamon Press, Oxford, 55 (1989)

[12] Williams PT, Williams EA, J. Anal. Appl. Pyrolysis., 51, 107 (1999)

[13] Bhaskar T, Murai K, Matsui T, Brebu MA, Uddin MA, Muto A, Sakata Y, Murata K, J. Anal. Appl. Pyrolysis., 70, 369 (2003)