Aurintricarboxylic acid (ATA), a UV absorbent, has successfully been intercalated into the interlayer spacing of Zn-Al-NO3-LDHs precursor through an anion-exchange reaction. The structure and the thermal- and photostability of the intercalated product were investigated by various techniques such as powder X-ray diffraction (XRD), infrared spectroscopy (FT-IR), thermogravimetry and differential thermal analysis (TG-DTA), and UV-vis spectroscopy. The increase of the basal spacing from 0.90 to 1.52 nm as observed by XRD suggests that the ATA anions have replaced the NO3- anions in the interlayer region of the precursor LDHs. The results of infrared spectroscopy and thermogravimetry and differential thermal analysis (TG-DTA) also reveal the presence of supramolecular host-guest interactions between the brucite-like sheet and the intercalated ATA anions. The intercalation of the ATA anions into the LDHs markedly enhances the thermal stability of this UV absorbent. After incorporation of 1 wt % ZnAl-ATA-LDHs to polypropylene (PP), also, the resulted ZnAl-ATA-LDHs/PP composite has much higher resistance to UV degradation related to PP.