"Depolymerization" Approach in Mn Cluster Chemistry: Controlled Cleavage of a 1D Coordination Polymer Consisting of Mn-8 Units in Its Constituent, Discrete Mn-8 Complex

Stoumpos CC; Roubeau O; Aromi G; Tasiopoulos AJ; Nastopoulos V; Escuer A; Perlepes SP

Inorganic Chemistry, Vol.49, No.2, 359-361, 2010

DOI10.1021/ic901974d Export Citation

"Depolymerization" Approach in Mn Cluster Chemistry: Controlled Cleavage of a 1D Coordination Polymer Consisting of Mn-8 Units in Its Constituent, Discrete Mn-8 Complex

Stoumpos CC, Roubeau O, Aromi G, Tasiopoulos AJ, Nastopoulos V, Escuer A, Perlepes SP

The cleavage of a 1D coordination polymer (mn(2)(II)mn(6)(III)), containing recognizable octanuclear units to obtain the discrete (Mn2Mn6III)-Mn-II cluster is reported.