Inorganic Chemistry, Vol.49, No.7, 3101-3103, 2010
Eicosanuclear Cluster [Cu13W7] of Copper-Octacyanotungstate Bimetallic Assembly: Synthesis, Structure, and Magnetic Properties
Octacyanotungstate(V) reacts with Cu(NO3)(2)center dot 2H(2)O and 1,4,7-trimethyl-1,4,7-triazacyclononane in methanol, resulting in an eicosanuclear cluster [Cu13W7], which shows a diamondoid shape with a Tolkowsky cut and bears intracluster ferromagnetic coupling.