Nitrile-Rich Coordination Polymer (1)(infinity){[Fe(CH3CN)(4)(pyrazine)](CIO4)(2)} Exhibiting a HS reversible arrow LS Transition

Bialonska A; Bronisz R; Darowska K; Drabent K; Kusz J; Siczek M; Weselski M; Zubko M; Zarowski A

Inorganic Chemistry, Vol.49, No.24, 11267-11269, 2010

DOI10.1021/ic102040y Export Citation

Nitrile-Rich Coordination Polymer (1)(infinity){[Fe(CH3CN)(4)(pyrazine)](CIO4)(2)} Exhibiting a HS reversible arrow LS Transition

Bialonska A, Bronisz R, Darowska K, Drabent K, Kusz J, Siczek M, Weselski M, Zubko M, Zarowski A

In a 1D network of (1)(infinity){[Fe(CH3CN)(4)(pyrazine)}(CIO4)(2)], the presence of four neutral nitrile molecules besides the pyrazine donors in the first coordination sphere of iron(II) allows one to achieve a ligand field strength appropriate for the "spin-crossover" occurrence.