[M(dap)(3)]InSb3S7 (M = Co, Ni): Two Novel Open-Framework Thioindate-Thioantimonates with 8-, 12-, and 16-Ring Intersecting Channels

Zhou JA; An LT; Zhang F

Inorganic Chemistry, Vol.50, No.2, 415-417, 2011

DOI10.1021/ic101912s Export Citation

[M(dap)(3)]InSb3S7 (M = Co, Ni): Two Novel Open-Framework Thioindate-Thioantimonates with 8-, 12-, and 16-Ring Intersecting Channels

Zhou JA, An LT, Zhang F

Two novel open-framewoik thioindate-thioantimonates [M(dap)(3)]-InSb3S7 [M = Co(1), Ni (2); dap = 1,2-diaminopropane] have been solvothermally synthesized and structurally characterized. 1 and 2 consist of InS4 tetrahedra and SbS33- trigonal pyramids, which are interconnected to form the first examples of three-dimensional In-Sb-S open frameworks with 8-, 12-, and 16-ring intersecting channels.