화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.36, No.3, 351-356, May, 2012
Export Citation
실란계 사슬 이동제를 사용한 아크릴 바인더의 제조
Preparation of Acryl Binder with Silane Type Chain Transfer Agent
김진곤, 신민재1, 신재섭†
  • 충북대학교 화학과
  • 1한국과학기술원 생명화공과
Jin Gon Kim, Min Jae Shin1, and Jae Sup Shin†
  • Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Korea
  • 1Department of Chemical and Biomolecular Engineering, KAIST, Daejeon 305-701, Korea
E-mail:
초록
디스플레이 전자 장치의 제작에 사용되는 대표적인 유기물첨가제는 아크릴 바인더이다. 이 아크릴 바인더는 라디칼 중합으로 제조되는데 본 연구에서는 glycidyl methacrylate(GMA), methyl methacrylate(MMA), methacrylic acid(MAA)를 이용하여 공중합을 시도하였다. 그리고 이 공중합체의 접착력 향상을 위해서 실란계 mercaptane 화합물을 사슬 이동제(CTA)로 사용하였다. 본 연구에서 사용된 CTA는 (3-mercaptopropyl) trimethoxysilane(MPTMS)이며, 제조된 공중합체들의 분자량, 코팅의 두께, 투과도, 접착력 등의 물성 등을 살펴보았다. 사용된 MPTMS 함량에 따라 분자량이 조절되었고, MPTMS의 함량이 증가할수록 접착력이 향상되었다.
Acryl binder is a representative organic additive for the manufacture of the display electronic equipment. Acryl binder is usually synthesized by radical copolymerization. Glycidyl methacrylate (GMA), methyl methacrylate (MMA), and methacrylic acid (MAA) were used in this copolymerization of acryl binder. In this study the silane type mercaptane compound was used as a chain transfer agent (CTA) to enhance the adhesion property of the acrylic binder. The CTA used in this experiment was (3-mercaptopropyl) trimethoxysilane (MPTMS). Molecular weight of the copolymer, thickness of the coating, transmittance, and adhesion property were measured. The molecular weight was controlled and the adhesion property was improved by using this silane type chain transfer agent.
Keywords:acryl binder;chain transfer agent;adhesion;(3-mercaptopropyl)trimethoxysilane.
  1. Brar AS, Yadav A, J. Mol. Struct., 602-603, 29 (2002)
  2. Nishikubo T, Takerhara E, Saita S, Matsumura T, J. Polym. Sci. Part A: Polym. Chem., 25, 3049 (1987)
  3. Subramanian K, Reddy AVR, J. Appl. Polym. Sci., 86(13), 3264 (2002)
  4. Lee JW, Kim JY, Kim TH, J. Korean Soc. Imaging Sci. Tech., 6, 39 (2000)
  5. Pyun HC, Park WB, Choi KS, Polymer(Korea)., 2, 269 (1979)
  6. Pyun HC, Park WB, Polym.(Korea), 6(4), 235 (1982)
  7. Park WB, Polym.(Korea), 7(4), 254 (1983)
  8. Mizutani Y, Kusukoto K, Kagiyama Y, J. Appl. Polym.Sci., 26, 271 (1981)
  9. Jialanella GL, Piirma I, J. Appl. Polym. Sci., 43, 1577 (1991)
  10. Vijayaraghavan PG, Reddy BS, J. Appl. Polym. Sci., 61(6), 935 (1996)
  11. Thamizharasi S, Gnanasundaram P, Reddy BS, J. Appl. Polym. Sci., 65(7), 1285 (1997)
  12. Becker D, Hage E, Pessan LA, J. Appl. Polym. Sci., 106(5), 3248 (2007)
  13. De La Fuente JL, Canamero PF, Fernandez-Garcia M, J. Polym. Sci. A: Polym. Chem., 44(6), 1807 (2006)
  14. Arun A, Reddy BSR, J. Polym. Res., 11, 195 (2004)
  15. Safa KD, Nasirtabrizi MH, Polym. Bull., 57(3), 293 (2006)
  16. Woo HG, Hong LY, Kim SY, Park SH, Bull.Korean Chem. Soc., 16, 774 (1995)
  17. Mouanda B, Polymer, 38(21), 5301 (1997)
  18. Wu YH, Wu CM, Gong M, Xu TW, J. Appl. Polym. Sci., 102(4), 3580 (2006)
  19. Han SH, Park KK, Lee SH, Macromol. Res., 17(1), 51 (2009)
  20. Wong KH, Stenzel MH, Duvall S, Ladouceur F, Chem. Mater., 22, 1878 (2010)
  21. Brandrup J, Immergut EH, Polymer Handbook, 4thed., Wiley, New York, p II2-69 (1999)
  22. Chung IS, Elastomer., 40, 53 (2005)
  23. Furuncuolu T, Uur I, Deirmenci I, Aviyente V, Macromolecules., 43, 1823 (1997)
  24. Hoyle CE, Lee TY, Roper T, J. Polym. Sci. A: Polym. Chem., 42(21), 5301 (2004)
  25. Zhao J, Chen M, An YQ, Liu JX, Yan FY, Appl. Surf. Sci., 255(5), 2295 (2008)
  26. Karimi Z, Mahjoub AR, Appl. Surf. Sci., 256(14), 4473 (2010)
  27. Ishizu K, Tokuno Y, Lee DH, Uchida S, Ozawa M, J. Appl. Polym. Sci., 112(4), 2434 (2009)
  28. Tian Y, Lu W, Shen LB, Jiang LM, Che Y, Shen ZQ, J. Appl. Polym. Sci., 115, 997 (2010)
  29. Chen JJ, Struk KN, Brennan AB, Langmuir., 27, 13754 (2011)
  30. Antonucci JM, Dickens SH, Fowler BO, Hockin HKX, Mcdonough WG, J. Res. Natl. Inst. Stand. Technol., 110, 541 (2005)
  31. Zhou F, Liu WM, Xu T, Liu SJ, Chen M, Liu JX, J. Appl. Polym. Sci., 92(3), 1695 (2004)
  32. Nakamura S, Pavlovic E, Kramer EJ, J. Adhes., 83, 351 (2007)
  33. Monni J, Alvila L, Rainio J, Pakkanen TT, J. Appl. Polym. Sci., 104(3), 1933 (2007)
  34. Kim S, Master Thesis, Seoul National University (2010)