Superhydrophilic organic/inorganic hybrid surfaces have been fabricated on blend membranes of poly(vinylidene fluoride) (PVDF) and poly(styrene-alt-maleic anhydride) (SMA). The blend membranes were prepared from PVDF/SMA mixed solution with N,N-dimethylacetamide (DMAc) as solvent by immersion-precipitation phase inversion process. The gained blend membranes were immersed into gamma-aminopropyltriethoxysilane (APTS) solution to generate SMA/silica hybrid surfaces by the reaction between anhydrides and APTS. The hybrid surfaces chemical compositions, morphologies and hydrophilicity were investigated in detail. It demonstrates that the hybrid surfaces possess micro-nano hierarchical structure and display superhydrophilicity property and good stability. Finally, the reaction and formation mechanism of the superhydrophilicity hybrid surface was discussed. (C) 2011 Elsevier Inc. All rights reserved.