Journal of Materials Science, Vol.46, No.17, 5798-5806, 2011
Grain refinement and mechanical properties enhancement of AZ91E alloy by addition of ceramic particles
Improved mechanical properties and structural uniformity of Mg-based alloys can be achieved by use of grain-refining additives prior to casting. Ceramic particles of alpha-Al(2)O(3) and SiC can serve as such additives to refine the microstructure of Mg-Al-based alloys. However, direct introduction of ceramic particles into Mg matrix is limited by the poor wetting of those particles by liquid Mg and their massive agglomeration. Mg/alpha-Al(2)O(3) and Mg/SiC master alloys were prepared using a method based on the insertion of the ceramic particles into a molten Mg bath through a Mg-nitride layer formed on the surface of the molten bath. The mixture of Mg/ceramic particles was cooled to room temperature under a nitrogen atmosphere. Mg-15%Al(2)O(3) and AZ91E + 10%SiC master alloys were obtained. These master alloys were used to refine AZ91E alloys by introducing various amounts of ceramic particles to manufacture AZ91E + 1%Al(2)O(3), AZ91E + 1%SiC, and AZ91E + 3%SiC alloys. These were cast using high-pressure die casting and gravity die casting. The alloy AZ91E + 1%Al(2)O(3) was grain refined to similar to 20 mu m and the alloys AZ91E + SiC were grain refined to similar to 50 mu m as against 110 mu m in non-refined counterparts. The mechanical properties of the modified alloys are substantially better than those of a non-refined AZ91E alloy which is the result of a combination of grain refinement and reinforcement of the matrix by ceramic particles. Alloy AZ91E + 1%Al(2)O(3) exhibited the best mechanical properties.