화학공학소재연구정보센터
Journal of Materials Science, Vol.47, No.11, 4680-4688, 2012
Formation mechanism and coarsening behavior of fan-type structures in a new Ni-Cr-Co-based powder metallurgy superalloy
The formation mechanism and coarsening behavior of fan-type structures in a new Ni-Cr-Co-based powder metallurgy superalloy were investigated by means of field scanning electron microscope, transmission electron microscope, electron backscattered diffraction, and differential scanning calorimetry. The results show that the fan-type structures consist of finger-shaped gamma' dendrites and c matrix between them. They nucleate in the chemical segregation regions on grain boundaries and grow by diffusion. There are three types of solute atoms flow: (a) rapid diffusion along grain boundary; (b) the diffusion from supersaturated c matrix to fan-type gamma' phases; and (c) short-distance diffusion from the previous formed gamma' phases at high temperature to gamma' phases formed at low temperature within the branches of fan-type structures. These gamma' dendrites are perpendicular to grain boundaries and grow asymmetrically, resulting in grain boundary serration. In addition, the fan-type structures coarsen within the gamma' depletion zone after the standard aging treatment.