The new technique to tailor carbon fabric-polyethersulphone (CF-PES) composite surface with polytetrafluoroethylene (PTFE) nano particles; to improve wear performance has been reported. Cold remote nitrogen oxygen plasma (CRNOP) treatment was employed to alter the CF surface to promote fiber/matrix adhesion and further; inter laminar shear strength and wear performance of the composites. The atomic force microscopy and high resolution transmission microscopy; studies confirms the topographical modification on the fiber surface due to CRNOP treatment. The dipper ridges and perforations introduced on the fiber surface were analyzed with field emission scanning electron microscopy. The PTFE particles film formation on the worn composite surface was supportively analyzed by Raman spectroscopy and energy dispersive X-ray techniques. The topographical smoothening and rolling effect during the wearing of surface designed composites with PTFE nano particles; endorse to enhance its sliding wear properties and life.