Adsorption characteristics of Reactive Black 5 onto chitosan beads cross-linked with epichlorohydrin

Tae-Young Kim; Seung-Shik Park; Sung-Yong Cho

Journal of Industrial and Engineering Chemistry, Vol.18, No.4, 1458-1464, July, 2012

DOI10.1016/j.jiec.2012.02.006 Export Citation

Adsorption characteristics of Reactive Black 5 onto chitosan beads cross-linked with epichlorohydrin

Tae-Young Kim¹, Seung-Shik Park¹, and Sung-Yong Cho^{1, 2, †}

¹Department of Environmental Engineering, Chonnam National University, Gwangju 500-757, Republic of Korea
²Environmental Research Institute, Chonnam National University, Gwangju 500-757, Republic of Korea

E-mail:

In this study, epichlorohydrin cross-linked chitosan beads were used for the removal of Reactive Black 5 (RB 5) from aqueous solution. The adsorption of RB 5 onto the cross-linked chitosan beads was strongly pH dependent. The adsorption capacity of RB 5 onto the cross-linked chitosan beads increased with increasing temperature, indicating the endothermic nature of the adsorption process. The thermodynamic parameters, namely the Gibbs free energy, enthalpy and entropy of the RB 5 adsorption process were calculated. The kinetic parameters were measured in a batch adsorber to analyze the rate of adsorption of RB 5 onto the cross-linked chitosan beads.

Keywords:Adsorption;Chitosan;Epichlorohydrin;Equilibrium;Kinetics;Reactive Black 5

[References]

Ahmad AA, Hameed BH, J. Hazard. Mater., 175(1-3), 298 (2010)
Tanyildizi MS, Chem. Eng. J., 168(3), 1234 (2011)
Dizge N, Aydiner C, Demirbas E, Kobya M, Kara S, J. Hazard. Mater., 150, 737 (2008)
Al-Degs Y, Khraisheh MAM, Allen SJ, Ahmad MN, Walker GM, Chem. Eng. J., 128(2-3), 163 (2007)
Baskaralingam P, Pulikesi M, Ramamurthi V, Sivanesan S, Appl. Clay Sci., 37, 207 (2007)
Sayan E, Chem. Eng. J., 119(2-3), 175 (2006)
Machado FM, Bergmann CP, Fernandes THM, Lima EC, Royer B, Calvete T, Fagan SB, J. Hazard. Mater., 192(3), 1122 (2011)
Leechart P, Nakbanpote W, Thiravetyan P, J. Environ. Manage., 90, 912 (2009)
Arica MY, Yilmaz M, Yalcin E, Bayramoglu G, J. Membr. Sci., 240(1-2), 167 (2004)
Wong YC, Szeto TS, Cheung WH, McKay G, Process Biochem., 39, 695 (2004)
Schmuhl R, Kreg HM, Keizer K, Water SA., 27, 1 (2001)
Hasan M, Ahmad AL, Hameed BH, Chem. Eng. J., 136(2-3), 164 (2008)
Kumar MNVR, React. Funct. Polym., 46, 1 (2000)
Wan Ngah WS, Fathinathan S, Colloid Surf. A: Physicochem. Eng. Aspects., 227, 214 (2006)
Wan Ngah WS, Endud CS, Mayanar R, React. Funct. Polym., 50, 181 (2002)
Wan Ngah WS, Hanafiah MAKM, Yong SS, Colloid Surf. B: Biointerfaces., 65, 18 (2008)
Annadurai G, Iran Polym. J., 11, 237 (2002)
Cestari AR, Vieira EFS, Pinto AA, Lopes ECN, J. Colloid Interface Sci., 292(2), 363 (2005)
Yoshida H, Okamoto A, Kataoka T, Chem. Eng. Sci., 48, 2267 (1993)
Han XL, Wang W, Ma XJ, Chem. Eng. J., 171(1), 1 (2011)
Jain AK, Gupta VK, Jain SS, Suhas, Environ. Sci. Technol., 38, 1195 (2004)
Misic DM, Sudo Y, Suzuki M, Kawazoe K, J. Chem. Eng. Japan., 15, 67 (1982)
Traegner UK, Suidan MT, Water Res., 23, 267 (1987)

[Referenced By]

[Related Articles]

[1] Ahmad AA, Hameed BH, J. Hazard. Mater., 175(1-3), 298 (2010)

[2] Tanyildizi MS, Chem. Eng. J., 168(3), 1234 (2011)

[3] Dizge N, Aydiner C, Demirbas E, Kobya M, Kara S, J. Hazard. Mater., 150, 737 (2008)

[4] Al-Degs Y, Khraisheh MAM, Allen SJ, Ahmad MN, Walker GM, Chem. Eng. J., 128(2-3), 163 (2007)

[5] Baskaralingam P, Pulikesi M, Ramamurthi V, Sivanesan S, Appl. Clay Sci., 37, 207 (2007)

[6] Sayan E, Chem. Eng. J., 119(2-3), 175 (2006)

[7] Machado FM, Bergmann CP, Fernandes THM, Lima EC, Royer B, Calvete T, Fagan SB, J. Hazard. Mater., 192(3), 1122 (2011)

[8] Leechart P, Nakbanpote W, Thiravetyan P, J. Environ. Manage., 90, 912 (2009)

[9] Arica MY, Yilmaz M, Yalcin E, Bayramoglu G, J. Membr. Sci., 240(1-2), 167 (2004)

[10] Wong YC, Szeto TS, Cheung WH, McKay G, Process Biochem., 39, 695 (2004)

[11] Schmuhl R, Kreg HM, Keizer K, Water SA., 27, 1 (2001)

[12] Hasan M, Ahmad AL, Hameed BH, Chem. Eng. J., 136(2-3), 164 (2008)

[13] Kumar MNVR, React. Funct. Polym., 46, 1 (2000)

[14] Wan Ngah WS, Fathinathan S, Colloid Surf. A: Physicochem. Eng. Aspects., 227, 214 (2006)

[15] Wan Ngah WS, Endud CS, Mayanar R, React. Funct. Polym., 50, 181 (2002)

[16] Wan Ngah WS, Hanafiah MAKM, Yong SS, Colloid Surf. B: Biointerfaces., 65, 18 (2008)

[17] Annadurai G, Iran Polym. J., 11, 237 (2002)

[18] Cestari AR, Vieira EFS, Pinto AA, Lopes ECN, J. Colloid Interface Sci., 292(2), 363 (2005)

[19] Yoshida H, Okamoto A, Kataoka T, Chem. Eng. Sci., 48, 2267 (1993)

[20] Han XL, Wang W, Ma XJ, Chem. Eng. J., 171(1), 1 (2011)

[21] Jain AK, Gupta VK, Jain SS, Suhas, Environ. Sci. Technol., 38, 1195 (2004)

[22] Misic DM, Sudo Y, Suzuki M, Kawazoe K, J. Chem. Eng. Japan., 15, 67 (1982)

[23] Traegner UK, Suidan MT, Water Res., 23, 267 (1987)