o-Xylene could be a good, candidate to represent the family of aromatic hydrocarbons in a surrogate fuel. This study uses computational chemistry to calculate standard enthalpies of formation it 298 K, Delta(f)H(o) (298 K), standard entropies at 298 K, S(o) (298 K), and standard heat capacities C(P)(o)(T) over the temperature range 300 K to 1500 K for ten target species present in the low temperature oxidation mechanism of o-xylene: o-xylene (1), 2-methylbenzyl radical (2), 2-methylbenzylperoxy radical (3), 2-methylbenzyl hydroperoxide (4), 2- (hydroperoxymethyl)benzyl radical (5), 2- (hydroperoxymethyl)benzaldehyde (6), 1-ethyl-2-methylbenzene (7), 2,3-dimethylphenol (8), 2-hydroxybenzaldehyde (9), and 3-hydroxybenzaldehyde (10); Delta(f)H(o)(298 K). values are weighted averages across the values calculated using five isodesmic reactions and five composite calculation methods: CBS-QB3, G3B3, G3MP2, G3, and G4. The uncertainty in Delta(f)H(o)(298 K) is also evaluated. S(o) (298 K) and C(P)(o)(T) values are calculated at B3LYP/67311G(d,p) level of theory from molecular properties and statistical thermodynamics through evaluation of translational, rotational, vibrational, and electronic partition functions. S(o) (298 K) and C(P)(o) (300 K) values are evaluated using the rigid-rotor-harmonic-oscillator model. C(p)(o) (T) values at T >= 400 K are calculated by treating separately internal rotation contributions and translational, external rotational, vibrational, and electronic contributions. The thermochemical properties of six target species are used to develop six new additivity groups taking into account the interaction between two substituents in ortho (ORT/CH2OOH/ME, ORT/ET/ME, ORT/CHO/OH, ORT/CHO/CH2OOH) or meta (MET/CHO/OH) positions, and the interaction between three substituents (ME/ME/OH123) located one beside the other (positions numbered 1, 2, 3) for two or three substituted benzenic species. Two other additivity groups are also developed using the thermochemical properties of benzenic species taken from the literature: the C/CB/H2/OO and the CB/CO groups. These groups extend the capacities of the group additivity method to deal with substituted benzenic species.