Journal of Polymer Science Part B: Polymer Physics, Vol.50, No.7, 477-483, 2012
Individual strings of conducting carbon cones and discs in a polymer matrix: Electric field-induced alignment and their use as a strain sensor
We demonstrate micromechanical strain sensors with integrated readout based on carbon nanocones and discs (CNCs) which are aligned into a string-like formation using an alternating electric field and studied by AC impedance spectroscopy and electromechanical methods. The CNC particles are first dispersed into a polymer matrix with a particle fraction of 0.1 vol %. This value is well below the percolation threshold (similar to 2 vol %), which suppresses particle aggregation and facilitates transparency allowing the use of an UV-curable polymer. Alignment was carried out with a 1 kHz, 4 kV/cm electric field and is a consequence of dielectrophoretic effect. It develops in minutes and makes the initially insulating, nonaligned material conductive. This is followed by UV curing of the polymer matrix, which renders a solid state device. The stretching of the aligned strings in the cured polymer leads to a reversible piezoresistive effect, and a gauge factor of about 50 is observed. This is in a sharp contrast to CNC films with particle fraction above percolation threshold (13 vol %), which are conductive but not sensitive to stretching. The strings are Ohmic in nature and moreover show higher DC conductivity (22500 S/m) compared to identically prepared carbon black strings (122 S/m). (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011
Keywords:composite materials;conducting polymers;microelectromechanical systems;sensors;biosensors;stimuli-responsive materials