Lanthanide (Ln(3+)) doped TiO2 down-conversion photoelectrodes (Ln(3+) = Eu3+ and Sm3+ ions) are used to enhance the photovoltaic efficiency of dye-sensitized solar cells (DSSC). We report on achieving fill factors of 0.67 and 0.69 and efficiencies of 5.81% and 5.16% for Sm3+ and Eu3+, respectively. This is compared to the 4.23% efficiency for the undoped-titania photoelectrodes. This enhancement is probably due to the improved UV radiation harvesting via a down-conversion luminescence process by the lanthanide ions. The structure, optical and photoluminescence properties of the down-converting photoelectrode are characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray (EDX) and room temperature photoluminescence excitation and emission spectrofluorimetric measurements. (C) 2011 Elsevier B.V. All rights reserved.