Novel hybrid membranes based on polybenzimidazole (PBI) and ETS-10 titanosilicate type materials functionalized with sulfonic groups have been developed for high temperature PEMFC applications. In particular, 45% porous ETS-10/PBI electrolyte membranes in porosity have been reported for the first time in this work. A clear conduction outperforming is shown by porous PBI + 3 wt.% SO(3)H-ETS-10 doped at 50 degrees C, attaining "in-plane" conductivity values up to 74 mS cm(-1) at 180 degrees C under dry N(2) flow. The transport selectivity of the as prepared dense and porous PBI based membranes has been evaluated by comparison of "in-plane" conductivity/methanol permeability values at 50 degrees C. 100 degrees C and 150 degrees C. Accounting from that, dense pure PBI membranes are preferred at 50 degrees C (4.7 x 10(6) S.s.bar mol(-1)); whereas at 150 degrees C, dense PBI + 3% SO(3)H-ETS-10 counterparts exhibit the higher conductivity/methanol permeability ratio (2.5 x 10(8) S.s.bar mol(-1)). (C) 2011 Elsevier B.V. All rights reserved.