Journal of Power Sources, Vol.196, No.24, 10788-10790, 2011
Converting rice husk activated carbon into active material for capacitor using three-dimensional porous current collector
We have successfully applied rice husk activated carbon (RHAC) as an active material for the electric double layer capacitor using a three-dimensional (3D) porous current collector. The capacity and cycle stability were evaluated in a 1.0 mol dm(-3) tetraethylammonium tetrafluoroborate/propylene carbonate solution in the range of 0-2.5 V. The specific capacity of the RHAC was about 14 mAh g(-1) at the 50 mA g(-1) discharge rate, corresponding to 19 F g(-1) under the present conditions. The RHAC cell using the 3D porous current collector possessed a lower internal resistance and better high-rate discharge properties than the RHAC cell using a conventional aluminum (Al) foil collector. After 5000 cycles of charging and discharging, the RHAC cell with the 3D current collector maintained 95% of its initial capacity, while the capacity of the one with the Al foil collector dropped to only 30%. (C) 2011 Elsevier B.V. All rights reserved.
Keywords:Rice husk activated carbon;Electric double layer capacitor;Three dimensional current collector;Internal resistance