Dramatic enhancement of catalytic activity over transition metal substituted hematite

Gajendra K. Pradhan; K.M. Parida

Journal of Industrial and Engineering Chemistry, Vol.18, No.5, 1612-1619, September, 2012

DOI10.1016/j.jiec.2012.02.022 Export Citation

Dramatic enhancement of catalytic activity over transition metal substituted hematite

Gajendra K. Pradhan, and K.M. Parida^†

Colloids and Materials Chemistry Department, Institute of Minerals & Materials Technology (CSIR), Bhubaneswar 751013, Odisha, India

E-mail:

This paper reports the fabrication of hematite (α-Fe2O3) and its mixed oxides (α-Fe2-xO3Cux, α-Fe2-xO3Cox, α-Fe2-xO3Nix) by hydrothermal technique without using any surface directing agent or capping agent. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The synthesized catalysts were screening for epoxidation of cyclohexene and trans-stilbene. Cu based mixed oxide shows almost two-fold higher conversion than pure hematite. Although we have not got significant conversion, but the epoxidation of the above two substrate over the hematite and its mixed oxide is new-fangled.

Keywords:Hematite;Mixed oxide;Epoxidation

[References]

Maruthamuthu P, Gurunathan K, Subramanian E, Ashok M, Chem. Soc. Jpn., 64, 1933 (1991)
Liu Q, MinCui Z, Ma Z, Bian SW, Song WG, Wan LJ, Nanotechnology., 18, 385605 (2007)
Wang G, Gou X, Horvat J, Park J, J. Phys. Chem. C., 112, 15220 (2008)
Rhodes FH, Burr CR, Webster PA, Ind. Eng. Chem., 16, 960 (1924)
Yigit MV, Mazumdar D, Lu Y, Bioconjug. Chem., 19, 412 (2008)
Mahmoudi M, Simchi A, Imani M, Hfeli UO, J. Phys. Chem. C., 113, 8124 (2009)
Khedr MH, Halimb KSA, Soliman NK, Mater. Lett., 63, 598 (2009)
Mohapatra SK, John SE, Banerjee S, Misra M, Chem. Mater., 21, 3048 (2009)
Glasscock JA, Barnes PRF, Plumb IC, Savvides N, J. Phys. Chem. C., 111, 16477 (2007)
Yousseff AM, Amin NM, Surf. Technol., 7, 469 (1978)
Shwarsctein AK, Hu YS, Forman AJ, Stucky GD, McFarland EW, J. Phys. Chem.C., 112, 15900 (2008)
Tailhades P, Sarda C, Bonino C, Mollard P, Rousset A, J. Magn. Magn. Mater., 89, 33 (1990)
de Souza AO, Rangel MD, React. Kinet. Catal. Lett., 79(1), 175 (2003)
Ingler WB, Baltrus JP, Khan SUM, J. Am. Chem. Soc., 126(33), 10238 (2004)
Wang SB, Min YL, Yu SH, J. Phys. Chem. C., 111, 3551 (2007)
Cao H, Wang G, Appl. Phys. Lett., 92, 013110 (2008)
Deng H, Li X, Peng Q, Wang X, Chen J, Li V, Angew. Chem. Int. Ed., 44, 2782 (2005)
Wu JJ, Lee YL, Chiang HH, Wong DKP, J. Phys. Chem. B, 110(37), 18108 (2006)
Almeida TP, Fay M, Zhu Y, Brown PD, J. Phys. Chem. C., 113, 186889 (2009)
Han Q, Liu Z, Xu Y, Chen Z, Wang T, Zhang H, J. Phys. Chem. C., 111, 5034 (2007)
Jia CJ, Sun LD, Yan ZG, You LP, Luo F, Han XD, Pang YC, Zhang Z, Yan CH, Angew. Chem. Int. Ed., 44, 4328 (2005)
Lv B, Xu Y, Wu D, Sun Y, Particuology., 6, 334 (2008)
Lu L, Ai Z, Li J, Zheng Z, Li Q, Zhang L, Cryst. Growth Des., 7, 459 (2007)
Wang H, Brand DW, Le F, Nordlander P, Halas NJ, Nano Lett., 6, 827 (2006)
Li S, Zhang H, Wu J, Ma X, Yang D, Cryst. Growth Des., 6, 351 (2006)
Cozzoli PD, Snoeck E, Garcia MA, Giannini C, Guagliardi A, Cervellino A, Gozzo F, Hernando A, Achterhold K, Ciobanu N, Parak FG, Cingolani R, Manna L, Nano Lett., 6, 1966 (2006)
Lee SH, Liddell CM, Small., 5, 1957 (2009)
Liang J, Tang QH, Meng GY, Wu HL, Zhang QH, Wang Y, Chem. Lett., 33(9), 1140 (2004)
Patil NS, Uphade BS, Jana P, Bharagava SK, Choudhary VR, J. Catal., 223(1), 236 (2004)
Ding Y, Gao Q, Li GX, Zhang HP, Wang JM, Yan L, Suo JS, J. Mol. Catal. A-Chem., 218(2), 161 (2004)
Kamata K, Kotani M, Yamaguchi K, Hikichi S, Mizuno N, Chem. Eur. J., 13, 639 (2007)
Bhattacharjee S, Dines TJ, Anderson JA, J. Phys. Chem. C., 112, 14124 (2008)
Choudhary VR, Jha R, Jana P, Catal. Commun., 10, 205 (2008)
Xu L, Sithambaram S, Zhang Y, Chen CH, Jin L, Joesten R, Suib SL, Chem. Mater., 21, 1253 (2009)
Choudhary VR, Jha R, Jana P, Green Chem., 8, 689 (2006)
Patil NS, Uphade BS, McCulloh DG, Bhargava SK, Choudhary VR, Catal.Commun., 5, 681 (2004)
Zhang DH, Li GD, Li JX, Chen JS, Chem. Commun., 3414 (2008)
An Z, Zhang J, Pan S, Yu F, J. Phys. Chem., C113, 8092 (2009)
Pradhan GK, Parida KM, Appl. Mater. Interf., 3, 317 (2011)
Cornell RM, Schwertmann U, The Iron Oxide Book, Second edition, 147 (2003)
Wagner CD, Riggs WM, Davis LE, Muilenberg JF, Handbook of X-ray Photoelectron Spectroscopy, Perkin Elmer (1979)
Bhargava G, Gouzman I, Chun CM, Ramanarayanan TA, Bernasek SL, Appl. Surf. Sci., 253(9), 4322 (2007)
Yamashita T, Hayes P, Appl. Surf. Sci., 254(8), 2441 (2008)
Grosvenor AP, Kobe BA, Biesinger MC, Mclntyre NS, Surf. Interface Anal., 36, 1564 (2004)
Stadnichenko AI, Sorokin AM, Boronin AI, J. Struct. Chem., 49, 341 (2008)
Alammar T, Birkner A, Mudring AV, Eur. J. Inorg. Chem., 2765 (2009)
Kim LS, Elect J, Spec. Rel. Pheno., 3, 217 (1974)
Frost DC, Ishitani A, Mcdowell CA, Mol. Phys., 24, 861 (1972)
Nagaraja BM, Padmasri AH, Raju BD, Rao KSR, J. Mol. Catal. A-Chem., 265(1-2), 90 (2007)
Leon CP, Kador L, Zhang M, Muller AHE, J. Raman. Spectrosc., 35 (2004)
Parida KM, Sahoo M, Singha S, 276, 161 (2010)
Mahtab P, Nasser S, Ali SA, Iran, J. Chem. Chem. Eng., 25, 85 (2006)

[Referenced By]

[1] Maruthamuthu P, Gurunathan K, Subramanian E, Ashok M, Chem. Soc. Jpn., 64, 1933 (1991)

[2] Liu Q, MinCui Z, Ma Z, Bian SW, Song WG, Wan LJ, Nanotechnology., 18, 385605 (2007)

[3] Wang G, Gou X, Horvat J, Park J, J. Phys. Chem. C., 112, 15220 (2008)

[4] Rhodes FH, Burr CR, Webster PA, Ind. Eng. Chem., 16, 960 (1924)

[5] Yigit MV, Mazumdar D, Lu Y, Bioconjug. Chem., 19, 412 (2008)

[6] Mahmoudi M, Simchi A, Imani M, Hfeli UO, J. Phys. Chem. C., 113, 8124 (2009)

[7] Khedr MH, Halimb KSA, Soliman NK, Mater. Lett., 63, 598 (2009)

[8] Mohapatra SK, John SE, Banerjee S, Misra M, Chem. Mater., 21, 3048 (2009)

[9] Glasscock JA, Barnes PRF, Plumb IC, Savvides N, J. Phys. Chem. C., 111, 16477 (2007)

[10] Yousseff AM, Amin NM, Surf. Technol., 7, 469 (1978)

[11] Shwarsctein AK, Hu YS, Forman AJ, Stucky GD, McFarland EW, J. Phys. Chem.C., 112, 15900 (2008)

[12] Tailhades P, Sarda C, Bonino C, Mollard P, Rousset A, J. Magn. Magn. Mater., 89, 33 (1990)

[13] de Souza AO, Rangel MD, React. Kinet. Catal. Lett., 79(1), 175 (2003)

[14] Ingler WB, Baltrus JP, Khan SUM, J. Am. Chem. Soc., 126(33), 10238 (2004)

[15] Wang SB, Min YL, Yu SH, J. Phys. Chem. C., 111, 3551 (2007)

[16] Cao H, Wang G, Appl. Phys. Lett., 92, 013110 (2008)

[17] Deng H, Li X, Peng Q, Wang X, Chen J, Li V, Angew. Chem. Int. Ed., 44, 2782 (2005)

[18] Wu JJ, Lee YL, Chiang HH, Wong DKP, J. Phys. Chem. B, 110(37), 18108 (2006)

[19] Almeida TP, Fay M, Zhu Y, Brown PD, J. Phys. Chem. C., 113, 186889 (2009)

[20] Han Q, Liu Z, Xu Y, Chen Z, Wang T, Zhang H, J. Phys. Chem. C., 111, 5034 (2007)

[21] Jia CJ, Sun LD, Yan ZG, You LP, Luo F, Han XD, Pang YC, Zhang Z, Yan CH, Angew. Chem. Int. Ed., 44, 4328 (2005)

[22] Lv B, Xu Y, Wu D, Sun Y, Particuology., 6, 334 (2008)

[23] Lu L, Ai Z, Li J, Zheng Z, Li Q, Zhang L, Cryst. Growth Des., 7, 459 (2007)

[24] Wang H, Brand DW, Le F, Nordlander P, Halas NJ, Nano Lett., 6, 827 (2006)

[25] Li S, Zhang H, Wu J, Ma X, Yang D, Cryst. Growth Des., 6, 351 (2006)

[26] Cozzoli PD, Snoeck E, Garcia MA, Giannini C, Guagliardi A, Cervellino A, Gozzo F, Hernando A, Achterhold K, Ciobanu N, Parak FG, Cingolani R, Manna L, Nano Lett., 6, 1966 (2006)

[27] Lee SH, Liddell CM, Small., 5, 1957 (2009)

[28] Liang J, Tang QH, Meng GY, Wu HL, Zhang QH, Wang Y, Chem. Lett., 33(9), 1140 (2004)

[29] Patil NS, Uphade BS, Jana P, Bharagava SK, Choudhary VR, J. Catal., 223(1), 236 (2004)

[30] Ding Y, Gao Q, Li GX, Zhang HP, Wang JM, Yan L, Suo JS, J. Mol. Catal. A-Chem., 218(2), 161 (2004)

[31] Kamata K, Kotani M, Yamaguchi K, Hikichi S, Mizuno N, Chem. Eur. J., 13, 639 (2007)

[32] Bhattacharjee S, Dines TJ, Anderson JA, J. Phys. Chem. C., 112, 14124 (2008)

[33] Choudhary VR, Jha R, Jana P, Catal. Commun., 10, 205 (2008)

[34] Xu L, Sithambaram S, Zhang Y, Chen CH, Jin L, Joesten R, Suib SL, Chem. Mater., 21, 1253 (2009)

[35] Choudhary VR, Jha R, Jana P, Green Chem., 8, 689 (2006)

[36] Patil NS, Uphade BS, McCulloh DG, Bhargava SK, Choudhary VR, Catal.Commun., 5, 681 (2004)

[37] Zhang DH, Li GD, Li JX, Chen JS, Chem. Commun., 3414 (2008)

[38] An Z, Zhang J, Pan S, Yu F, J. Phys. Chem., C113, 8092 (2009)

[39] Pradhan GK, Parida KM, Appl. Mater. Interf., 3, 317 (2011)

[40] Cornell RM, Schwertmann U, The Iron Oxide Book, Second edition, 147 (2003)

[41] Wagner CD, Riggs WM, Davis LE, Muilenberg JF, Handbook of X-ray Photoelectron Spectroscopy, Perkin Elmer (1979)

[42] Bhargava G, Gouzman I, Chun CM, Ramanarayanan TA, Bernasek SL, Appl. Surf. Sci., 253(9), 4322 (2007)

[43] Yamashita T, Hayes P, Appl. Surf. Sci., 254(8), 2441 (2008)

[44] Grosvenor AP, Kobe BA, Biesinger MC, Mclntyre NS, Surf. Interface Anal., 36, 1564 (2004)

[45] Stadnichenko AI, Sorokin AM, Boronin AI, J. Struct. Chem., 49, 341 (2008)

[46] Alammar T, Birkner A, Mudring AV, Eur. J. Inorg. Chem., 2765 (2009)

[47] Kim LS, Elect J, Spec. Rel. Pheno., 3, 217 (1974)

[48] Frost DC, Ishitani A, Mcdowell CA, Mol. Phys., 24, 861 (1972)

[49] Nagaraja BM, Padmasri AH, Raju BD, Rao KSR, J. Mol. Catal. A-Chem., 265(1-2), 90 (2007)

[50] Leon CP, Kador L, Zhang M, Muller AHE, J. Raman. Spectrosc., 35 (2004)

[51] Parida KM, Sahoo M, Singha S, 276, 161 (2010)

[52] Mahtab P, Nasser S, Ali SA, Iran, J. Chem. Chem. Eng., 25, 85 (2006)