A novel approach for itaconic acid extraction: Mixture of trioctylamine and tridodecylamine in different diluents

Yavuz Selim Asci; Ismail Inci

Journal of Industrial and Engineering Chemistry, Vol.18, No.5, 1705-1709, September, 2012

DOI10.1016/j.jiec.2012.03.010 Export Citation

A novel approach for itaconic acid extraction: Mixture of trioctylamine and tridodecylamine in different diluents

Yavuz Selim Asci^†, and Ismail Inci

Engineering Faculty, Chemical Engineering Department, Istanbul University, 34320 Istanbul, Turkey

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Extraction of itaconic acid has been investigated from aqueous solutions by six kind of different solutions of trioctylamine (TOA)-tridodecylamine (TDA) mixtures. Solvents have selected as dimethyl phthalate(DMP), methyl isobutyl ketone (MIBK), 2-octanone, 1-octanol, cyclohexyleacetate (CHA), and 1-decanol. Distribution and equilibrium data for design of separation equipments have been obtained as a result of batch extraction of itaconic acid. It has been calculated that distribution coefficients (D), loading factors (Z), extraction efficiency (E). The maximum removal of itaconic acid has been obtained as 98.39% with DMP and 3.14 mol L^(-1) initial concentration of TOA-TDA mixture.

Keywords:Extraction;Itaconic acid;Amine mixture

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[2] Muralidhara Rao D, Hussain SMDJ, Rangadu VP, Subramanyam K, Krishna GS, Swamy AVN, Afr. J. Biotechnol., 6, 2140 (2007)

[3] Baup S, Ann. Chim. Phys., 19, 29 (1837)

[4] Kinoshita K, Acta Phytochim., 5, 271 (1932)

[5] Shekhawat D, Jackson JE, Miller DJ, Bioresour. Technol., 97(2), 342 (2006)

[6] Petuchow AG, Tschernowa NG, Tischtschow WA, Belenkaja NK, Method of producing itaconic acid, SU-Patent 732,379 (1980)

[7] Kumar S, Datta D, Babu BV, Chem. Eng. Process., 50(7), 614 (2011)

[8] Lockwood LB, Reeves MD, Arch. Biochem., 6, 455 (1945)

[9] Nelson G, Traufler DH, Kelley SE, Lockwood LB, Ind. Eng. Chem., 44, 1166 (1952)

[10] Pfeifer VF, Vojnovich C, Heger EN, Ind. Eng. Chem., 44, 2975 (1952)

[11] Wasewar KL, Shende D, Keshav A, Ind. Eng. Chem. Res., 50(2), 1003 (2011)

[12] Tuyun AF, Uslu H, J. Chem. React. Eng., 9, A29 (2011)

[13] Soni AB, Keshav A, Verma V, Suresh S, Int. J. Environ. Res., 6, 297 (2011)

[14] Ascı YS, Hasdemir IM, Chem. Eng. Data., 53, 2351 (2008)

[15] Datta D, Kumar S, Ind. Eng. Chem. Res., 50(5), 3041 (2011)

[16] Uslu H, Kirbaslar SI, Fluid Phase Equilib., 287(2), 134 (2010)

[17] Tuyun AF, Uslu H, Desalination, 268(1-3), 134 (2011)

[18] Keshav A, Wasewar KL, Chand S, Sep. Purif. Technol., 63(1), 179 (2008)

[19] Tuyun AF, Uslu H, Gokmen S, Yorulmaz Y, J. Chem. Eng. Data., 56, 2310 (2011)

[20] Kumar TP, Vishwanadham B, Rani KNP, Mallikarjun M, Rao VVB, Chem.Eng.Commun., 198(4), 572 (2010)

[21] Ascı YS, I˙nci I, J. Chem. Eng. Data., 55, 847 (2010)

[22] Keshav K, Chand S, Wasewar KL, J. Chem. Eng. Data., 54, 1782 (2009)

[23] Levien BA, J. Phys. Chem., 59, 640 (1955)

[24] I˙nci I, Uslu H, Ayhan ST, J. Chem. Eng. Data., 50(3), 961 (2005)

[25] Ascı YS, I˙nci I, J. Chem. Eng. Data., 55(7), 2385 (2010)