Core-shell polymerization for monodispersed hollow polymer spheres embedded with magnetic nanoparticles

Nam Seon Kim; Jong-Duk Kim

Journal of Industrial and Engineering Chemistry, Vol.18, No.5, 1721-1729, September, 2012

DOI10.1016/j.jiec.2012.03.012 Export Citation

Core-shell polymerization for monodispersed hollow polymer spheres embedded with magnetic nanoparticles

Nam Seon Kim^{1, 2}, and Jong-Duk Kim^{2, †}

¹R&D Center, Aekyung Chemical Co., 217-2 Shinseong-dong, Yuseong-Gu, Daejeon 305-805, Republic of Korea
²Dept. of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Republic of Korea

E-mail:

Monodispersed hollow polymers embedded with Fe3O4 nanoparticles were prepared by core-shell polymerization applied to both the hydrophobic surface and hydrophilic surface of the magnetic nanoparticles. The void size and polymer shell thickness of these hollow polymers can be easily tuned over a wide range. The final magnetic hollow polymers were characterized by dynamic light scattering (DLS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA) and magnetic force microscopy (MFM) and confirmed to form capsules embedded with magnetic nanoparticles. These magnetic hollow polymers were stably dispersed in an aqueous phase and were intrinsically superparamagnetic because of the presence of magnetic nanoparticles.

Keywords:Magnetic hollow polymer;Core-shell polymerization;Fe3O4 nanoparticle;Colloidal stability

[References]

Xu XL, Asher SA, J. Am. Chem. Soc., 126(25), 7940 (2004)
An K, Hyeon T, Nano Today., 4, 359 (2009)
Cheng K, Peng S, Xu CJ, Sun SH, J. Am. Chem. Soc., 131(30), 10637 (2009)
Lou XW, Archer LA, Yang ZC, Adv. Mater., 20(21), 3987 (2008)
Kondo Y, Yoshikawa H, Awaga K, Murayama M, Mori T, Sunada K, Bandow S, Iijima S, Langmuir, 24(2), 547 (2008)
Yu JG, Yu XX, Huang BB, Zhang XX, Dai Y, Cryst. Growth Des., 9, 1474 (2009)
Wu ZL, Yu K, Zhang SD, Xie Y, J. Phys. Chem. C., 112, 11307 (2008)
Chang YE, Youn DY, Ankonina G, Yang DJ, Kim HG, Rothschild A, Kim ID, Chem. Commun., 4019 (2009)
Liu ZF, Ding T, Zhang G, Song K, Clays K, Tung CH, Langmuir, 24(18), 10519 (2008)
Ye QL, Kozuka Y, Yoshikawa H, Awaga K, Bandow S, Iijima S, Phys. Rev. B., 224404:1, 75 (2007)
Ohnish M, Kozuka Y, Ye QL, Yoshikawa H, Awaga K, Matsuno R, Kobayashi M, Takahara A, Yokoyama T, Bandow S, Iijima S, J. Mater. Chem., 16, 3215 (2006)
Cabot A, Alivisatos AP, Puntes VF, Balcells L, Iglesias O, Labarta A, Phys. Rev. B., 094419:1., 79 (2009)
Huang J, Chen WM, Zhao W, Li YQ, Li XG, Chen CP, J. Phys. Chem. C., 113, 12067 (2009)
Wang X, Yuan FL, Hu P, Yu LJ, Bai LJ, Phys. Chem. C., 112, 8773 (2008)
Zhu LP, Xiao HM, Zhang WD, Yang G, Fu SY, Cryst. Growth Des., 8, 957 (2008)
Hu P, Yu LJ, Zuo AH, Guo CY, Yuan FL, J. Phys. Chem. C., 113, 900 (2009)
Vasquez Y, Sra AK, Schaak RE, J. Am. Chem. Soc., 127(36), 12504 (2005)
Zhang K, Wu W, Guo K, Chen JF, Zhang PY, Colloids Surf. A: Physicochem. Eng.Aspects., 349, 110 (2009)
Koo HY, Chang ST, Choi WS, Park JH, Kim DY, Orlin DV, Chem. Mater., 18, 3308 (2006)
Kowalski A, Vogel M, Blankenship, US Patent 4,427,836 (1984)
He XD, Ge XW, Wang MZ, Zhang ZC, J. Appl. Polym. Sci., 98(2), 860 (2005)
Kang YS, Risbud S, Rabolt JF, Stroeve P, Chem. Mater., 8, 2209 (1996)
Wang J, Xu CH, Yao M, Chen J, Xu GJ, J. Nanopart. Res., 12, 1161 (2010)
Yang YH, Wen ZK, Dong YP, Gao MY, Small., 2, 898 (2006)
Yang YH, Tu CF, Gao MY, J. Mater. Chem., 17, 2930 (2007)
Li HL, Li P, Yang Y, Qi W, Sun H, Wu LX, Macromol. Rapid Commun., 29(5), 431 (2008)
Tu CF, Yang YH, Gao MY, Nanotechnology., 19, 8 (2008)
Song GP, Bo J, Guo R, Chin. J. Chem., 23, 997 (2005)
Shimoiizaka J, Nakatsuka K, Fujita T, Kounosu A, Fine particles, Processing-Proceedings of the international symposium on fine particles processing, vol. 2, In: P. Somasundaran (Ed.), New York (1980)
Pamirez LP, Landfester K, Macromol. Chem. Phys., 204, 22 (2003)

[Referenced By]

[Related Articles]

[1] Xu XL, Asher SA, J. Am. Chem. Soc., 126(25), 7940 (2004)

[2] An K, Hyeon T, Nano Today., 4, 359 (2009)

[3] Cheng K, Peng S, Xu CJ, Sun SH, J. Am. Chem. Soc., 131(30), 10637 (2009)

[4] Lou XW, Archer LA, Yang ZC, Adv. Mater., 20(21), 3987 (2008)

[5] Kondo Y, Yoshikawa H, Awaga K, Murayama M, Mori T, Sunada K, Bandow S, Iijima S, Langmuir, 24(2), 547 (2008)

[6] Yu JG, Yu XX, Huang BB, Zhang XX, Dai Y, Cryst. Growth Des., 9, 1474 (2009)

[7] Wu ZL, Yu K, Zhang SD, Xie Y, J. Phys. Chem. C., 112, 11307 (2008)

[8] Chang YE, Youn DY, Ankonina G, Yang DJ, Kim HG, Rothschild A, Kim ID, Chem. Commun., 4019 (2009)

[9] Liu ZF, Ding T, Zhang G, Song K, Clays K, Tung CH, Langmuir, 24(18), 10519 (2008)

[10] Ye QL, Kozuka Y, Yoshikawa H, Awaga K, Bandow S, Iijima S, Phys. Rev. B., 224404:1, 75 (2007)

[11] Ohnish M, Kozuka Y, Ye QL, Yoshikawa H, Awaga K, Matsuno R, Kobayashi M, Takahara A, Yokoyama T, Bandow S, Iijima S, J. Mater. Chem., 16, 3215 (2006)

[12] Cabot A, Alivisatos AP, Puntes VF, Balcells L, Iglesias O, Labarta A, Phys. Rev. B., 094419:1., 79 (2009)

[13] Huang J, Chen WM, Zhao W, Li YQ, Li XG, Chen CP, J. Phys. Chem. C., 113, 12067 (2009)

[14] Wang X, Yuan FL, Hu P, Yu LJ, Bai LJ, Phys. Chem. C., 112, 8773 (2008)

[15] Zhu LP, Xiao HM, Zhang WD, Yang G, Fu SY, Cryst. Growth Des., 8, 957 (2008)

[16] Hu P, Yu LJ, Zuo AH, Guo CY, Yuan FL, J. Phys. Chem. C., 113, 900 (2009)

[17] Vasquez Y, Sra AK, Schaak RE, J. Am. Chem. Soc., 127(36), 12504 (2005)

[18] Zhang K, Wu W, Guo K, Chen JF, Zhang PY, Colloids Surf. A: Physicochem. Eng.Aspects., 349, 110 (2009)

[19] Koo HY, Chang ST, Choi WS, Park JH, Kim DY, Orlin DV, Chem. Mater., 18, 3308 (2006)

[20] Kowalski A, Vogel M, Blankenship, US Patent 4,427,836 (1984)

[21] He XD, Ge XW, Wang MZ, Zhang ZC, J. Appl. Polym. Sci., 98(2), 860 (2005)

[22] Kang YS, Risbud S, Rabolt JF, Stroeve P, Chem. Mater., 8, 2209 (1996)

[23] Wang J, Xu CH, Yao M, Chen J, Xu GJ, J. Nanopart. Res., 12, 1161 (2010)

[24] Yang YH, Wen ZK, Dong YP, Gao MY, Small., 2, 898 (2006)

[25] Yang YH, Tu CF, Gao MY, J. Mater. Chem., 17, 2930 (2007)

[26] Li HL, Li P, Yang Y, Qi W, Sun H, Wu LX, Macromol. Rapid Commun., 29(5), 431 (2008)

[27] Tu CF, Yang YH, Gao MY, Nanotechnology., 19, 8 (2008)

[28] Song GP, Bo J, Guo R, Chin. J. Chem., 23, 997 (2005)

[29] Shimoiizaka J, Nakatsuka K, Fujita T, Kounosu A, Fine particles, Processing-Proceedings of the international symposium on fine particles processing, vol. 2, In: P. Somasundaran (Ed.), New York (1980)

[30] Pamirez LP, Landfester K, Macromol. Chem. Phys., 204, 22 (2003)