Preparation of highly carbonized material from nanoparticle impregnated biomass

Jin-Woo Kim; Chae-Ho Shin; Joong-Hwan Park; Wen-Zhu Jin; Kwan-Ho Bae; Maeng-Joon Jung

Journal of Industrial and Engineering Chemistry, Vol.18, No.5, 1828-1835, September, 2012

DOI10.1016/j.jiec.2012.04.012 Export Citation

Preparation of highly carbonized material from nanoparticle impregnated biomass

Jin-Woo Kim, Chae-Ho Shin , Joong-Hwan Park¹, Wen-Zhu Jin², Kwan-Ho Bae³, and Maeng-Joon Jung^{2, †}

Department of Chemical Engineering, ChungBuk National University, 52 Naesudong-ro, Heungdeok-gu, Cheongju, Chungbok 361-763, Republic of Korea
¹DR C&C Co., Ltd., 507 Mikon Techno World I, 533 Yongsan-dong, Yusung-gu, Daejon 305-500, Republic of Korea
²Department of Nano & Materials Science and Engineering, Kyungpook National University, 386 Gajang-dong, Sangju, Gyeongsangbuk-do 742-711, Republic of Korea
³Department of Ecology & Environmental System, Kyungpook National University, 386 Gajang-dong, Sangju, Gyeongsangbuk-do 742-711, Republic of Korea

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In this study, we impregnated nanometal samples having various concentrations 0, 1000, 3000, and 5000 ppm in biomass in order to make carbonized biomass. We analyzed the properties of the impregnated samples through thermogravimetry/differential thermal analysis (TG-DTA), iodine adsorptivity, fixed carbon ratio, pore distribution, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The best results were observed for a nanometal concentration of 5000 ppm. After the first heat treatment, carbonization, and activation processes, the fixed carbon ratio and iodine adsorptivity were increased by 11.07% and 42 mg/g, 11.07% and 198 mg/g, and 46.7% and 1185 mg/g, respectively. Through repeated experiments, we established the most effective process for impregnating a nanometal in biomass.

Keywords:Biomass;Nanometal;Pyrolysis;TGA;Fixed carbon

[References]

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Tanada S, Kawasaki N, Nakamura T, Araki M, Isomura M, J. Colloid Interface Sci., 214(1), 106 (1999)
Kwon SM, Kim NH, Mokchae Konghak., 24(3), 8 (2006)
Shin SK, Kang JH, Song JH, Journal of KSEE., 32(10), 936 (2010)
Kim BR, Lee JY, Mokchae Konghak., 34(1), 40 (2006)
Jo TS, Ahn BJ, Choi DH, Mokchae Konghak., 33(3), 45 (2005)
Jo TS, Lee OK,Ahn BJ, Choi HW, J. Kor. For. En., 25(1), 9 (2006)
Figueiredo JL, Pereira MFR, Freitas MMA, Orfao JJM, Carbon., 37, 1379 (1999)
Pulido-Novicio L, Hata T, Kurimoto Y, Dio S, Ishihara S, Imamira Y, Journal of Wood Science., 47, 48 (2001)
Youssef AM, El-Nabarawy T, Samra SE, Colloids and Surfaces A., 235, 153 (2004)
Lim JK, Lee SW, Kam SK, Lee DW, Lee MG, Journal of the Environmental Sciences., 14(1), 61 (2005)
Teng H, Wang SC, Carbon., 38, 817 (2000)
Nakamura A, Inui T, Kinomura N, Suzuki T, Carbon., 38, 1361 (2000)
Milina-Sabio M, Rodriguez-Reinoso F, catarla F, Selles MJ, Carbon., 33, 1105 (1995)
Otawa T, Nojima Y, Miyazaki T, Carbon., 35, 1315 (1997)
Ibana JV, Moliner R, Palacios JM, Fuel., 70, 727 (1991)
Oh WC, Kim BS, Lee YS, J. Korean Ind. Eng. Chem., 11(2), 212 (2000)
Oh WC, Kim BS, Lee YS, Ko YS, Proceeding of First World Conf. on Carbon, Berlin.
Fengel D, Wegener G, Wood: Chemistry, Ultrastructure, Reaction, Walter de Gruyter, (Chapter 3). (1993)
Hon DNS, Chemical Modification of Lignocellulosic Materials, Marcel Dekker, New York (1996)
Raveendran K, Ganesh A, Khilar KC, Fuel., 75, 987 (1996)
Demirbas A, Energy Conv. Manag., 41(6), 633 (2000)
Caballero JA, Conesa JA, Font R, Marcilla A, Journal of Analytical and Applied Pyrolysis., 42, 159 (1997)
Broido A, Nelson MA, Combustion and Flame., 24, 263 (1975)
Kifanisahban F, Kifani A, Belkbir L, Zoulalian A, Arauzo J, Cardero T, Thermochim. Acta, 298(1-2), 199 (1997)
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Antal MJ, Varhegyi G, Ind. Eng. Chem. Res., 34(3), 703 (1995)

[Referenced By]

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[1] Demirbas A, Energy Conv. Manag., 42(11), 1357 (2001)

[2] Tanada S, Kawasaki N, Nakamura T, Araki M, Isomura M, J. Colloid Interface Sci., 214(1), 106 (1999)

[3] Kwon SM, Kim NH, Mokchae Konghak., 24(3), 8 (2006)

[4] Shin SK, Kang JH, Song JH, Journal of KSEE., 32(10), 936 (2010)

[5] Kim BR, Lee JY, Mokchae Konghak., 34(1), 40 (2006)

[6] Jo TS, Ahn BJ, Choi DH, Mokchae Konghak., 33(3), 45 (2005)

[7] Jo TS, Lee OK,Ahn BJ, Choi HW, J. Kor. For. En., 25(1), 9 (2006)

[8] Figueiredo JL, Pereira MFR, Freitas MMA, Orfao JJM, Carbon., 37, 1379 (1999)

[9] Pulido-Novicio L, Hata T, Kurimoto Y, Dio S, Ishihara S, Imamira Y, Journal of Wood Science., 47, 48 (2001)

[10] Youssef AM, El-Nabarawy T, Samra SE, Colloids and Surfaces A., 235, 153 (2004)

[11] Lim JK, Lee SW, Kam SK, Lee DW, Lee MG, Journal of the Environmental Sciences., 14(1), 61 (2005)

[12] Teng H, Wang SC, Carbon., 38, 817 (2000)

[13] Nakamura A, Inui T, Kinomura N, Suzuki T, Carbon., 38, 1361 (2000)

[14] Milina-Sabio M, Rodriguez-Reinoso F, catarla F, Selles MJ, Carbon., 33, 1105 (1995)

[15] Otawa T, Nojima Y, Miyazaki T, Carbon., 35, 1315 (1997)

[16] Ibana JV, Moliner R, Palacios JM, Fuel., 70, 727 (1991)

[17] Oh WC, Kim BS, Lee YS, J. Korean Ind. Eng. Chem., 11(2), 212 (2000)

[18] Oh WC, Kim BS, Lee YS, Ko YS, Proceeding of First World Conf. on Carbon, Berlin.

[19] Fengel D, Wegener G, Wood: Chemistry, Ultrastructure, Reaction, Walter de Gruyter, (Chapter 3). (1993)

[20] Hon DNS, Chemical Modification of Lignocellulosic Materials, Marcel Dekker, New York (1996)

[21] Raveendran K, Ganesh A, Khilar KC, Fuel., 75, 987 (1996)

[22] Demirbas A, Energy Conv. Manag., 41(6), 633 (2000)

[23] Caballero JA, Conesa JA, Font R, Marcilla A, Journal of Analytical and Applied Pyrolysis., 42, 159 (1997)

[24] Broido A, Nelson MA, Combustion and Flame., 24, 263 (1975)

[25] Kifanisahban F, Kifani A, Belkbir L, Zoulalian A, Arauzo J, Cardero T, Thermochim. Acta, 298(1-2), 199 (1997)

[26] Erickson M, Miksche GE, Holzfoschung., 27, 147 (1973)

[27] Antal MJ, Varhegyi G, Ind. Eng. Chem. Res., 34(3), 703 (1995)