화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.18, No.5, 1845-1850, September, 2012
DOI10.1016/j.jiec.2012.04.014  Export Citation
Production of elemental sulfur and ammonium thiosulfate by the oxidation of H2S containing water vapor and ammonia over V/Zr-PILC catalysts
Kanattukara Vijayan Bineesh, Moon-il Kim, Goo-Hwa Lee, Manickam Selvaraj, Kyu Hyun, and Dae-Won Park†
  • School of Chemical and Biomolecular Engineering, Pusan National University, Busan 609-735, Republic of Korea
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The catalytic oxidation of hydrogen sulfide in the presence of water and ammonia was studied over V2O5 supported on Zr-pillared clay catalysts (V/Zr-PILCs). The synthesized catalysts were examined using a variety of characterization techniques. A catalytic performance study using V/Zr-PILC catalysts showed that H2S was successfully converted to elemental sulfur and ammonium thiosulfate (ATS) without considerable emission of sulfur dioxide. The H2S conversion over V/Zr-PILCs increased with increasing the content of vanadia up to 6 wt.%. This superior catalytic performance might be related to the uniform dispersion of vanadia species on the Zr-PILC support.
Keywords:Selective catalytic oxidation;Hydrogen sulfide;Sulfur;Pillared clay;Vanadia
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