Journal of the American Chemical Society, Vol.134, No.4, 2172-2179, 2012
Quantum Phase Transition from Superparamagnetic to Quantum Superparamagnetic State in Ultrasmall Cd1-xCr(II)(x)Se Quantum Dots?
Despite a long history of success in formation of transition-metal-doped quantum dots (QDs), the origin or magnetism in diluted magnetic semiconductors (DMSs) is yet a controversial issue. Cr(II)-doped II-VI DMSs are half-metallic, resulting in high-temperature ferromagnetism. The magnetic properties reflect a strong p-d exchange interaction between the spin-up Cr(II) t(2g) level and the Se 4p. In this study, ultrasmall (similar to 3.1 nm) Cr(II)-doped CdSe DMSQDs are shown to exhibit room-temperature ferromagnetism, as expected from theoretical arguments. Surprisingly, a low-temperature phase transition is observed at 20 K that is believed to reflect the onset of long-range ordering of the single-domain DMSQD.