화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.134, No.14, 6128-6131, 2012
Up to 4 Orders of Magnitude Enhancement of Crown Ether Complexation in an Aqueous Phase Coexistent with Ice
Ice chromatography measurements have revealed anomalous enhancements of crown ether complexation in a liquid phase coexistent with ice. The 4 orders of magnitude enhancement was confirmed for the complexation of dibenzo-24-crown-8 in sub-pm-sized liquid inclusions formed in ice doped with <1 mM NaCl or KCl. This enhancement became less pronounced with increasing dopant concentration.