Materials Chemistry and Physics, Vol.129, No.3, 718-728, 2011
Calculation of phase equilibria in Ti-Al-Cr-Mn quaternary system for developing lower cost titanium alloys
The Ti-Al-Cr-Mn system is a potentially useful system for lower cost titanium alloy development; however, there are few reports about the experimental phase diagrams and the thermodynamical assessment for this system. In this study, the previous investigations for the thermodynamic descriptions of the subsystems in the Ti-Al-Cr-Mn system are reviewed, our previous assessment for the related sub-systems in this quaternary system is summarized, the thermodynamical database of this quaternary system is built up by directly extrapolating from all sub-systems assessed by means of the Calphad method, then the pseudobinary sections with Cr:Mn = 3:1 and Al = 0.0, 3.0, 4.5 and 6.0 wt% are calculated, respectively. These pseudobinary phase diagrams may provide the theoretical support for designing the lower cost titanium alloys with different microstructures (alpha, alpha + beta, and beta titanium alloy). (C) 2011 Elsevier B.V. All rights reserved.
Keywords:Alloys;Intermetallic compounds;Computer modelling and simulation;Microstructure;Phase equilibria