Submicron-sized NiFe2O4 particles were synthesized by the molten salt method at 900 degrees C using binary melts of a NaCl and KCl mixture that acts as a flux. The X-ray diffraction pattern confirmed the single phase, high crystalline and cubic structure of NiFe2O4 with a Fd3m space group. The FT-IR spectra reveal the stretching vibration of octahedral complexes of Fe3+-O2- through the observed band around 552.3 cm(-1). The SEM and TEM image had indicated the formation of submicron-sized NiFe2O4 particles. The ferrimagnetic behavior and high saturation magnetization of 44 emu g(-1) was elucidated by VSM. The maximum electrical conductivity of 1.42 x 10(-4) S cm(-1) was observed at 873 K. The NiFe2O4 showed a pseudocapacitive property in 1 M of a LiClO4 electrolyte and exhibited a specific capacitance of 18.5 Fg(-1) at 10 mV s(-1). The hydrogen evolution reaction was also studied for NiFe2O4 in 1 M of a H2SO4 solution. (C) 2011 Elsevier B.V. All rights reserved.