화학공학소재연구정보센터
Polymer, Vol.52, No.18, 4001-4010, 2011
Fabrication of exfoliated graphene-based polypropylene nanocomposites with enhanced mechanical and thermal properties
Despite the great potential of graphene as the nanofiller, to achieve homogeneous dispersion remains the key challenge for effectively reinforcing the polymer. Here, we report an eco-friendly strategy for fabricating the polymer nanocomposites with well-dispersed graphene sheets in the polymer matrix via first coating graphene using polypropylene (PP) latex and then melt-blending the coated graphene with PP matrix. A similar to 75% increase in yield strength and a similar to 74% increase in the Young's modulus of PP are achieved by addition of only 0.42 vol% of graphene due to the effective external load transfer. The glass transition temperature of PP is enhanced by similar to 2.5 degrees C by incorporating only 0.041 vol% graphene. The thermal oxidative stability of PP is also remarkably improved with the addition of graphene, for example, compared with neat PP, the initial degradation temperature is enhanced by 26 degrees C at only 0.42 vol% of graphene loading. (C) 2011 Elsevier Ltd. All rights reserved.