Polymer Bulletin, Vol.68, No.1, 239-251, 2012
The effects of vibration field on crystal structures and orientation of isotactic polypropylene injection samples
In this study, isotactic polypropylene (iPP) samples were prepared by self-made pressure vibration injection device, in which a periodical shear field was imposed on the iPP melt during the filling and packing stages. The crystal structures and orientation of samples were investigated by wide-angle X-ray diffraction and polarizing light microscopy (PLM). The beta form and gamma form were found in vibration injection molding samples. Compared with the static samples, the orientation of iPP chains within lamellae was observed in the transition layer (at the depth of 1.5 mm from the surface) of the vibration injection molding samples, and the orientation was found even in the core layer. The PLM observation indicates the beta form exists in the transition and core region of the vibration sample. Besides, two types of beta-PP could be observed simultaneously in the core region under high magnification. The bright beta crystallites (beta(III)) are fan-shaped and lie perpendicularly to the flow direction. In the other hand, the ringed beta crystallites (beta(IV)) almost remain their spherulite shape. Moreover, fiber crystal was observed in vibration sample, even in the core region. Some fiber crystals in the transition region reappeared in the cooling circle after the sample was held at 180 A degrees C for 2 min. This could be explained in structure memory effect and its high thermal stability.
Keywords:Vibration injection molding;Crystal structures;Orientation;beta poly (propylene) (PP);Structure memory effect