Thermochimica Acta, Vol.523, No.1-2, 70-78, 2011
New experimental investigation of the lanthanum zinc phase diagram
After careful review of literature, the La-Zn phase diagram is reinvestigated by X-ray diffraction, scanning electron microscopy, microprobe analysis and differential thermal analyses. A more accurate description of the diagram is proposed. Among the eight intermetallic compounds, LaZn, LaZn2 and La2Zn17 melt congruently whereas LaZn4, LaZn5, La3Zn22, LaZn11, and LaZn13 decompose peritectically. The diagram includes four eutectic and one metatectic invariant reactions. (C) 2011 Elsevier B.V. All rights reserved.