The effect of heating and cooling rates on the DSC (differential scanning calorimetry) heat flux peak of the monoclinic-tetragonal transition of zirconia was investigated in the 0.4-20 degrees C/min scan rate range. While the peak position, shape and area at high to moderate scan rates are consistent with existing literature data, a 'step change' (i.e., a peak-less baseline shift) was observed for the extremely slow heating rate of 0.4 degrees C/min. As expected, peak profiles in the heating and cooling transitions are markedly different, the peak shape being strongly asymmetrical for the t -> m transition, but very closely symmetrical for the m -> t transition. As the cooling rate is lowered, the t -> m peak is increasingly splitted into multiple components, whose individual properties have been fitted using Gamma distribution functions. (C) 2011 Elsevier B.V. All rights reserved.