The catalysts of COOH- and SO3H-functionalized ionic liquids mediated metallic salts had been developed for the coupling of carbon dioxide and epoxides to form cyclic carbonates under mild reaction conditions without using additional organic solvents. The effects of different ionic liquids, metallic salts, varying the molar ratio of ionic liquid to metallic salt and reaction conditions were examined. The excellent yield of cyclic carbonates and the high turnover frequencies (TOF) were obtained at the optimum reaction conditions. In addition, the catalytic system offered high stability and reusability.