화학공학소재연구정보센터
Composite Interfaces, Vol.18, No.1, 57-76, 2011
Assessing the Influence of Porosity in the Deformation of Metal-Ceramic Composites
The aim of the paper is to develop the previously formulated model [19, 20] of the polycrystalline composite to include porosity growth at metallic interfaces of metal-ceramic composites (MCCs). Examples of this kind of MCCs are: (1) a two-phase material composed of brittle grains WC joined by the plastic binder Co, which can contain a small degree of porosity introduced during the cooling process [31], (2) TiC-Mo2C hard phase grains surrounded by tough binder phase Ni [12]. This work focuses on the description of the deformation of the MCC material including the modelling of a real material internal structure taking into account porosity growth during the loading. Experimental observations of the WC/Co composite [10] indicate that the majority of the fracture energy of MCC is expended through ductile failure of the plastic binder Co (dimple rupture across the binder or in the binder near the binder/carbide interface). This process is preceded by porosity growth at metallic interfaces and finally leads to inter-granular cracks propagation. This paper presents micromechanical modelling of the MCC response in the case of uniaxial tension of 3-D Representative Volume Element (RVE) with the application of the Finite Element Analysis (FEA). The MCC material includes: elastic grains and inter-granular metallic layers containing technological pores that create its real complex internal structure. The quasi-static deformation process of the material comprises elastic deformation of brittle grains, elasto-plastic deformation of inter-granular layers (of different thickness: 2-4 mu m) and additional deformation due to micro-porosity development in the layers. A micro-sample analysis leads to the conclusion that a small amount of technological porosity changes the qualitative behaviour of the MCC including deformation, rotation of grains, roughness, and level of plastic strains. (C) Koninklijke Brill NV, Leiden, 2011