International Journal of Hydrogen Energy, Vol.23, No.12, 1079-1085, 1998
First experimental establishment of high internal pressure of molecular hydrogen developed in palladium during water electrolysis
The paper aims at examining the hypothesis of high internal pressure within voids in metals. The method used was to form a void space inside a cylindrical electrode coupled to a pressure transducer. In about 1000 h a pressure of about 280 atm was measured. It has been shown that Slow diffusion of hydrogen into the void space prevents the attainment in a practical time of st theoretical pressure of similar to 10(3) aim.