Inorganic Chemistry, Vol.51, No.10, 5503-5505, 2012
High Nuclearity in Azido/Oximate Chemistry: Ni-14 and Ni-13 Clusters with S=6 and 9 Ground States
In the present work, we report a family of Ni-14 and unprecedented Ni-13 clusters linked by end-on azido and oximato bridges. Ferrimagnetic response gives S = 6 and 9 ground states, resulting in the largest nuclearities and spins in nickel oximato chemistry.