A light-duty diesel engine has been operated in advanced combustion modes known generally as pre-mixed charge compression ignition (PCCI). The emissions have been characterized for several load and speed combinations. Fewer NO and particulate matter (PM) emissions are produced by PCCI, but higher CO and hydrocarbon (HC) emissions result. In addition, the nature of the PM differs from conventional combustion; the PM is smaller and has a much higher soluble organic fraction (SOF) content (68% vs. 30% for conventional combustion). Three catalyst technologies were studied to determine the affects of HECC on catalyst performance; the technologies were a lean NO(x) trap (LNT), diesel oxidation catalyst (DOC), and diesel particulate filter (DPF). The LNT benefited greatly from the reduced NO(x) emissions associated with PCCI. NO capacity requirements are reduced as well as overall tailpipe NO(x) levels particularly at low load and temperature conditions where regeneration of the LNT is difficult. The DOC performance requirements for PCCI are more stringent due to the higher CO and HC emissions; however, the DOC was effective at controlling the higher CO and HC emissions at conditions above the light-off temperature. Below light-off, CO and HC emissions are problematic. The study of DPF technology focused on the fuel penalties associated with DPF regeneration or "desoot" due to the different PM loading rates from PCCI vs. conventional combustion. Less frequent desoot events were required from the lower PM from PCCI and, when used in conjunction with an LNT, the lower PM from less frequent LNT regeneration. The lower desoot frequency leads a similar to 3% fuel penalty for a mixture of PCCI and conventional loads vs. similar to 4% for conventional only combustion. (C) 2010 Elsevier B.V. All rights reserved.