Catalysis Today, Vol.155, No.1-2, 35-44, 2010
Technology of methane combustion on granulated catalysts for environmentally friendly gas turbine power plants
The technology of methane combustion in small gas turbine catalytic combustors on alternative granulated catalysts with a low content of noble metals has been developed and studied. The operations of catalyst packages for environmentally clean combustion consisting of one-, two-or three catalysts with different chemical composition, shape and size of granules have been analyzed. The optimized design of a three-stage catalyst package with total height of 340 mm includes 40 mm of highly active Pd-Ce-Al(2)O(3) at the entrance of the combustion chamber in the form of 7.5 mm x 7.5 mm x 2.5 mm rings; 240 mm of a basic catalyst based on Mn-hexaaluminate with the granules of the same form and size; and 60 mm of Pd-Mn-La-Al(2)O(3) catalyst as 4-5 mm spherical granules at the exit of the combustion chamber. Such optimal design yielded methane combustion over 99.97% at T(inlet) = 470-580 degrees C and oxygen excess coefficient 5.2-7.0. The emission levels were NO(x) < 1 ppm, CO < 10 ppm, HC < 10 ppm. The pressure drop across the catalyst package was less than 4% of the total pressure (1 bar). (C) 2010 Elsevier B.V. All rights reserved.
Keywords:Methane catalytic combustion;Gas turbine power plant;Pd-ceria catalyst;Pd-hexaaluminate catalyst