Catalysis Today, Vol.156, No.3-4, 246-253, 2010
Influence of the oxygen feed distribution on the performance of a catalytic reactor for ATR of methane
In the present contribution, a theoretical study of a multitubular membrane reactor (MR) for the autothermal reforming of methane (ATR) over a Ni/MgOAl(2)O(3) catalyst is presented. By means of a pseudo-homogeneous 1D model, the viability and convenience of the proposed design to produce hydrogen to feed a PEM fuel cell of 10 kW(th) is analyzed. The influence of the operating conditions on the reactor behavior is studied. The results suggest that the MR is a promising alternative to conventional reactors to carry out ATR of methane at milder conditions and with similar H(2) productions. The axial distribution of the O(2) fed to the reactor is a powerful tool to influence the axial temperature profiles, the methane conversion and the selectivity. However, the reactor should be operated carefully, to avoid operating conditions where an accumulation phenomenon of oxygen along the axial axis appears. (C) 2010 Elsevier B.V. All rights reserved.