Fe-Ce-Mn/ZSM-5 catalysts were prepared and performance of catalysts in NO selective catalytic reduction by NH3 was tested in the temperature range of 100-500 degrees C. NO conversion reached 96.6% and 98.1% at 200 degrees C and 300 degrees C respectively at a GHSV of 30,000 h(-1). In situ diffuse reflectance infrared transform spectroscopy (DRIFTS) study was carried out for revealing the reaction mechanism. Two possible reaction pathways were proposed. One was that NO2 could react with NH4+ on Bronsted acid sites and the formed NO2[NH4+](2) would react with NO, producing N-2 and H2O. Another way was that NH3 was adsorbed and then reacted with NO or HNO2. Possible intermediate NH4NO2 and NH2NO were unstable and would decompose into N-2 and H2O. The addition of Mn in Fe-Ce-Mn/ZSM-5 catalysts could contribute to provide more Bronsted acid sites which was beneficial for the adsorption of NH3. The addition of both Fe and Ce could obviously increase the conversion of NO to NO2. Introduction of Fe increased the oxidation of NH3 slightly and the addition of Ce increased the oxidation of NH3 significantly. The combination of manganese, iron and cerium could significantly enhance the low temperature SCR activity. (C) 2011 Elsevier B.V. All rights reserved.