In the paper, the influences of water flux on both discharge current and onset voltage were studied. Both charging and capturing particles of atomizing corona discharges were investigated when the magnetic field was used or not. The charge number of droplets and their sizes were calculated after some parameters were measured by Millikan oil drop instrument. In addition, the capturing ability of atomizing corona discharge pre-charger with magnetic field was compared with the traditional pre-charger. Eventually, the charging mechanism of atomizing corona discharge with magnetic field was analyzed through the above-mentioned experimentation and comparison. The result shows that the smallest onset voltage will appear with water flow increase in the atomizing corona discharge, and that the ion concentration between electrodes is the highest in the atomizing corona discharge charger with magnetic field than any other pre-charger, which is conducive for charging dust particles. Hence the new pre-charging technique is promising for capturing fine aerosol particles in electrostatic precipitators. (C) 2011 Elsevier B. V. All rights reserved.